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The influence of polymer purification on the efficiency of poly(3-hexylthiophene):fullerene organic solar cells.

ABSTRACT: We report the influence of different polymer purification procedures on the photovoltaic performance of bulk heterojunction solar cells formed from binary blends of poly(3-hexylthiophene) (P3HT) and fullerenes. Selective Soxhlet extractions and metal scavenging agents were used to remove residual monomer, magnesium salt by-products and catalyst from high-weight P3HT (Mw 121?kg/mol, PDI 1.8, RR 99%) synthesised by the Grignard metathesis (GRIM) polymerization route. Using phenyl-C61-butyric acid methyl ester (PC60BM) as an electron acceptor, we observed an increase in average power conversion efficiency from 2.3 to 4.8% in going from crude to fully purified material. Using indene-C60 bisadduct (IC60BA) in place of PC60BM, we observed a further increase to an average value of 6.6% - high for a bulk heterojunction formed from a binary blend of P3HT and C60 fullerene derivatives.

SUBMITTER: Bannock JH

PROVIDER: S-EPMC4814819 | biostudies-other | 2016 Mar

REPOSITORIES: biostudies-other

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The influence of polymer purification on the efficiency of poly(3-hexylthiophene):fullerene organic solar cells.

Bannock James H JH Treat Neil D ND Chabinyc Michael M Stingelin Natalie N Heeney Martin M de Mello John C JC

Scientific reports 20160331

We report the influence of different polymer purification procedures on the photovoltaic performance of bulk heterojunction solar cells formed from binary blends of poly(3-hexylthiophene) (P3HT) and fullerenes. Selective Soxhlet extractions and metal scavenging agents were used to remove residual monomer, magnesium salt by-products and catalyst from high-weight P3HT (Mw 121 kg/mol, PDI 1.8, RR 99%) synthesised by the Grignard metathesis (GRIM) polymerization route. Using phenyl-C61-butyric acid ...[more]

PMID: 27029994

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