Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Novel Rechargeable M3V2(PO4)3//Zinc (M = Li, Na) Hybrid Aqueous Batteries with Excellent Cycling Performance.

ABSTRACT: A rechargeable hybrid aqueous battery (ReHAB) containing NASICON-type M3V2(PO4)3 (M = Li, Na) as the cathodes and Zinc metal as the anode, working in Li2SO4-ZnSO4 aqueous electrolyte, has been studied. Both of Li3V2(PO4)3 and Na3V2(PO4)3 cathodes can be reversibly charge/discharge with the initial discharge capacity of 128 mAh g(-1) and 96 mAh g(-1) at 0.2C, respectively, with high up to 84% of capacity retention ratio after 200 cycles. The electrochemical assisted ex-XRD confirm that Li3V2(PO4)3 and Na3V2(PO4)3 are relative stable in aqueous electrolyte, and Na3V2(PO4)3 showed more complicated electrochemical mechanism due to the co-insertion of Li(+) and Na(+). The effect of pH of aqueous electrolyte and the dendrite of Zn on the cycling performance of as designed MVP/Zn ReHABs were investigated, and weak acidic aqueous electrolyte with pH around 4.0-4.5 was optimized. The float current test confirmed that the designed batteries are stable in aqueous electrolytes. The MVP//Zn ReHABs could be a potential candidate for future rechargeable aqueous battery due to their high safety, fast dynamic speed and adaptable electrochemical window. Moreover, this hybrid battery broadens the scope of battery material research from single-ion-involving to double-ions -involving rechargeable batteries.

SUBMITTER: Zhao HB

PROVIDER: S-EPMC4865945 | biostudies-other | 2016

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Similar Datasets

Long-lived Aqueous Rechargeable Lithium Batteries Using Mesoporous LiTi2(PO4)3@C Anode.

Project description:The instability of anode materials during cycling has been greatly limiting the lifetime of aqueous rechargeable lithium batteries (ARLBs). Here, to tackle this issue, mesoporous LiTi2(PO4)3@C composites with a pore size of 4 nm and a large BET surface area of 165 m(2) g(-1) have been synthesized by a novel two-step approach. The ARLB with this type of LiTi2(PO4)3@C anode, commercial LiMn2O4 cathode and 2 M Li2(SO4) aqueous solution (oxygen was removed) exhibited superior cycling stability (a capacity retention of 88.9% after 1200 cycles at 150 mA g(-1) and 82.7% over 5500 cycles at 750 mA g(-1)) and excellent rate capability (discharge capacities of 121, 110, 90, and 80 mAh g(-1) based on the mass of LiTi2(PO4)3 at 30, 150, 1500, and 3000 mA g(-1), respectively). As verified, the mesoporous structure, large surface area and high-quality carbon coating layer of the LiTi2(PO4)3@C composite contribute to the breakthrough in achieving excellent electrochemical properties for ARLB.

| S-EPMC4673533 | biostudies-literature

Development of rechargeable high-energy hybrid zinc-iodine aqueous batteries exploiting reversible chlorine-based redox reaction.

Project description:The chlorine-based redox reaction (ClRR) could be exploited to produce secondary high-energy aqueous batteries. However, efficient and reversible ClRR is challenging, and it is affected by parasitic reactions such as Cl2 gas evolution and electrolyte decomposition. Here, to circumvent these issues, we use iodine as positive electrode active material in a battery system comprising a Zn metal negative electrode and a concentrated (e.g., 30 molal) ZnCl2 aqueous electrolyte solution. During cell discharge, the iodine at the positive electrode interacts with the chloride ions from the electrolyte to enable interhalogen coordinating chemistry and forming ICl3-. In this way, the redox-active halogen atoms allow a reversible three-electrons transfer reaction which, at the lab-scale cell level, translates into an initial specific discharge capacity of 612.5 mAh gI2-1 at 0.5 A gI2-1 and 25 °C (corresponding to a calculated specific energy of 905 Wh kgI2-1). We also report the assembly and testing of a Zn | |Cl-I pouch cell prototype demonstrating a discharge capacity retention of about 74% after 300 cycles at 200 mA and 25 °C (final discharge capacity of about 92 mAh).

| S-EPMC10070632 | biostudies-literature

Rechargeable Aqueous Zinc-Ion Batteries in MgSO<sub>4</sub>/ZnSO<sub>4</sub> Hybrid Electrolytes.

Project description:MgSO4 is chosen as an additive to address the capacity fading issue in the rechargeable zinc-ion battery system of MgxV2O5·nH2O//ZnSO4//zinc. Electrolytes with different concentration ratios of ZnSO4 and MgSO4 are investigated. The batteries measured in the 1 M ZnSO4-1 M MgSO4 electrolyte outplay other competitors, which deliver a high specific capacity of 374 mAh g-1 at a current density of 100 mA g-1 and exhibit a competitive rate performance with the reversible capacity of 175 mAh g-1 at 5 A g-1. This study provides a promising route to improve the performance of vanadium-based cathodes for aqueous zinc-ion batteries with electrolyte optimization in cost-effective electrolytes.

| S-EPMC7770650 | biostudies-literature

Zinc-Ion Storage Mechanism of Polyaniline for Rechargeable Aqueous Zinc-Ion Batteries.

Project description:Aqueous multivalent ion batteries, especially aqueous zinc-ion batteries (ZIBs), have promising energy storage application due to their unique merits of safety, high ionic conductivity, and high gravimetric energy density. To improve their electrochemical performance, polyaniline (PANI) is often chosen to suppress cathode dissolution. Herein, this work focuses on the zinc ion storage behavior of a PANI cathode. The energy storage mechanism of PANI is associated with four types of protonated/non-protonated amine or imine. The PANI cathode achieves a high capacity of 74 mAh g-1 at 0.3 A g-1 and maintains 48.4% of its initial discharge capacity after 1000 cycles. It also demonstrates an ultrahigh diffusion coefficient of 6.25 × 10-9~7.82 × 10-8 cm-2 s-1 during discharging and 7.69 × 10-10~1.81 × 10-7 cm-2 s-1 during charging processes, which is one or two orders of magnitude higher than other reported studies. This work sheds a light on developing PANI-composited cathodes in rechargeable aqueous ZIBs energy storage devices.

| S-EPMC9103876 | biostudies-literature

Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities.

Project description:Although alkaline zinc-manganese dioxide batteries have dominated the primary battery applications, it is challenging to make them rechargeable. Here we report a high-performance rechargeable zinc-manganese dioxide system with an aqueous mild-acidic zinc triflate electrolyte. We demonstrate that the tunnel structured manganese dioxide polymorphs undergo a phase transition to layered zinc-buserite on first discharging, thus allowing subsequent intercalation of zinc cations in the latter structure. Based on this electrode mechanism, we formulate an aqueous zinc/manganese triflate electrolyte that enables the formation of a protective porous manganese oxide layer. The cathode exhibits a high reversible capacity of 225?mAh?g-1 and long-term cyclability with 94% capacity retention over 2000 cycles. Remarkably, the pouch zinc-manganese dioxide battery delivers a total energy density of 75.2?Wh?kg-1. As a result of the superior battery performance, the high safety of aqueous electrolyte, the facile cell assembly and the cost benefit of the source materials, this zinc-manganese dioxide system is believed to be promising for large-scale energy storage applications.The development of rechargeable aqueous zinc batteries are challenging but promising for energy storage applications. With a mild-acidic triflate electrolyte, here the authors show a high-performance Zn-MnO2 battery in which the MnO2 cathode undergoes Zn2+ (de)intercalation.

| S-EPMC5581336 | biostudies-literature

Redox-active zinc thiolates for low-cost aqueous rechargeable Zn-ion batteries.

Project description:Aqueous zinc-ion batteries (AZIBs) are promising candidates for large-scale electrical energy storage due to the inexpensive, safe, and non-toxic nature of zinc. One key area that requires further development is electrode materials that store Zn2+ ions with high reversibility and fast kinetics. To determine the viability of low-cost organosulfur compounds as OEMs for AZIBs, we investigate how structural modification affects electrochemical performance in Zn-thiolate complexes 1 and 2. Remarkably, modification of one thiolate in 1 to sulfide in 2 reduces the voltage hysteresis from 1.04 V to 0.15 V. While 1 exhibits negligible specific capacity due to the formation of insulating DMcT polymers, 2 delivers a capacity of 107 mA h g-1 with a primary discharge plateau at 1.1 V vs. Zn2+/Zn. Spectroscopic studies of 2 suggest a Zn2+ and H+ co-insertion mechanism with Zn2+ as the predominant charge carrier. Capacity fading in Zn-2 cells likely results from the formation of (i) soluble H+ insertion products and (ii) non-redox-active side products. Increasing electrolyte concentration and using a Nafion membrane significantly enhances the stability of 2 by suppressing H+ insertion. Our findings provide insight into the molecular design strategies to reduce the polarization potential and improve the cycling stability of the thiolate/disulfide redox couple in aqueous battery systems.

| S-EPMC8635210 | biostudies-literature

Reaction mechanisms for electrolytic manganese dioxide in rechargeable aqueous zinc-ion batteries.

Project description:This study reports the phase transformation behaviour associated with electrolytic manganese dioxide (EMD) utilized as the positive electrode active material for aqueous zinc-ion batteries. Electrochemical techniques, including galvanostatic charge-discharge and rotating ring-disk electrode measurements, and microstructural techniques, using X-ray powder diffraction, scanning electron microscopy, and transmission/scanning transmission electron microscopy, were utilized to characterize the positive electrode at different stages of discharge and charge of zinc-ion cells. The results indicate that, during discharge, a fraction of EMD undergoes a transformation to ZnMn2O4 (spinel-type) and Zn2+ is intercalated into the tunnels of the γ- and ε-MnO2 phases, forming ZnxMnO2 (tunnel-type). When a critical concentration of Mn3+ in the intercalated ZnxMnO2 species is reached, a disproportionation/dissolution reaction is triggered leading to the formation of soluble Mn2+ and hydroxide (OH-) ions; the latter precipitates as zinc hydroxide sulfate (ZHS, Zn4(OH)6(SO4)·5H2O) by combination with the ZnSO4/H2O electrolyte. During charge, Zn2+ is reversibly deintercalated from the intergrown tunneled phases (γ-/ε-ZnxMnO2), Mn2+ is redeposited as layered chalcophanite (ZnMn3O7·3H2O), and ZHS is decomposed by protons (H+) formed during the electrochemical deposition of chalcophanite.

| S-EPMC8531032 | biostudies-literature

New-concept batteries based on aqueous Li+/Na+ mixed-ion electrolytes.

Project description:Rechargeable batteries made from low-cost and abundant materials operating in safe aqueous electrolytes are attractive for large-scale energy storage. Sodium-ion battery is considered as a potential alternative of current lithium-ion battery. As sodium-intercalation compounds suitable for aqueous batteries are limited, we adopt a novel concept of Li(+)/Na(+) mixed-ion electrolytes to create two batteries (LiMn2O4/Na0.22MnO2 and Na0.44MnO2/TiP2O7), which relies on two electrochemical processes. One involves Li(+) insertion/extraction reaction, and the other mainly relates to Na(+) extraction/insertion reaction. Two batteries exhibit specific energy of 17 Wh kg(-1) and 25 Wh kg(-1) based on the total weight of active electrode materials, respectively. As well, aqueous LiMn2O4/Na0.22MnO2 battery is capable of separating Li(+) and Na(+) due to its specific mechanism unlike the traditional "rocking-chair" lithium-ion batteries. Hence, the Li(+)/Na(+) mixed-ion batteries offer promising applications in energy storage and Li(+)/Na(+) separation.

| S-EPMC3672879 | biostudies-other

Poly(benzoquinonyl sulfide) as a High-Energy Organic Cathode for Rechargeable Li and Na Batteries.

Project description:In concern of resource sustainability and environmental friendliness, organic electrode materials for rechargeable batteries have attracted increasing attentions in recent years. However, for many researchers, the primary impression on organic cathode materials is the poor cycling stability and low energy density, mainly due to the unfavorable dissolution and low redox potential, respectively. Herein, a novel polymer cathode material, namely poly(benzoquinonyl sulfide) (PBQS) is reported, for either rechargeable Li or Na battery. Remarkably, PBQS shows a high energy density of 734 W h kg-1 (2.67 V × 275 mA h g-1) in Li battery, or 557 W h kg-1 (2.08 V × 268 mA h g-1) in Na battery, which exceeds those of most inorganic Li or Na intercalation cathodes. Moreover, PBQS also demonstrates excellent long-term cycling stability (1000 cycles, 86%) and superior rate capability (5000 mA g-1, 72%) in Li battery. Besides the exciting battery performance, investigations on the structure-property relationship between benzoquinone (BQ) and PBQS, and electrochemical behavior difference between Li-PBQS battery and Na-PBQS battery, also provide significant insights into developing better Li-organic and Na-organic batteries beyond conventional Li-ion batteries.

| S-EPMC5115381 | biostudies-literature

A high capacity small molecule quinone cathode for rechargeable aqueous zinc-organic batteries.

Project description:Rechargeable aqueous zinc-organic batteries are promising energy storage systems with low-cost aqueous electrolyte and zinc metal anode. The electrochemical properties can be systematically adjusted with molecular design on organic cathode materials. Herein, we use a symmetric small molecule quinone cathode, tetraamino-p-benzoquinone (TABQ), with desirable functional groups to protonate and accomplish dominated proton insertion from weakly acidic zinc electrolyte. The hydrogen bonding network formed with carbonyl and amino groups on the TABQ molecules allows facile proton conduction through the Grotthuss-type mechanism. It guarantees activation energies below 300 meV for charge transfer and proton diffusion. The TABQ cathode delivers a high capacity of 303 mAh g-1 at 0.1 A g-1 in a zinc-organic battery. With the increase of current density to 5 A g-1, 213 mAh g-1 capacity is still preserved with stable cycling for 1000 times. Our work proposes an effective approach towards high performance organic electrode materials.

| S-EPMC8292436 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data