Ontology highlight
ABSTRACT:
SUBMITTER: Jentzen W
PROVIDER: S-EPMC4988798 | biostudies-other | 2016 Jun
REPOSITORIES: biostudies-other
Jentzen Walter W Shelnutt John A JA Scheidt W Robert WR
Inorganic chemistry 20160608 12
Procedures for the purification and subsequent crystallization of the slightly soluble four-coordinate metallporphines, the simplest possible porphyrin derivatives, are described. Crystals of the porphine derivatives of cobalt(II), copper(II), platinum(II), and two polymorphs of zinc(II) were obtained. Analysis of the crystal and molecular structures shows that all except the platinum(II) derivative form an unusual trimeric species in the solid state. The isomorphous cobalt(II), copper(II), and ...[more]