Dataset Information

A novel ethanol gas sensor based on TiO2/Ag0.35V2O5 branched nanoheterostructures.

ABSTRACT: Much greater surface-to-volume ratio of hierarchical nanostructures renders them attract considerable interest as prototypical gas sensors. In this work, a novel resistive gas sensor based on TiO2/Ag0.35V2O5 branched nanoheterostructures is fabricated by a facile one-step synthetic process and the ethanol sensing performance of this device is characterized systematically, which shows faster response/recovery behavior, better selectivity, and higher sensitivity of about 9 times as compared to the pure TiO2 nanofibers. The enhanced sensitivity of the TiO2/Ag0.35V2O5 branched nanoheterostructures should be attributed to the extraordinary branched hierarchical structures and TiO2/Ag0.35V2O5 heterojunctions, which can eventually result in an obvious change of resistance upon ethanol exposure. This study not only indicates the gas sensing mechanism for performance enhancement of branched nanoheterostructures, but also proposes a rational approach to design nanostructure based chemical sensors with desirable performance.

SUBMITTER: Wang Y

PROVIDER: S-EPMC5018879 | biostudies-other | 2016

REPOSITORIES: biostudies-other

ACCESS DATA

Publications

A novel ethanol gas sensor based on TiO2/Ag0.35V2O5 branched nanoheterostructures.

Wang Yuan Y Liu Lixin L Meng Chuanmin C Zhou Yun Y Gao Zhao Z Li Xuhai X Cao Xiuxia X Xu Liang L Zhu Wenjun W

Scientific reports 20160912

Much greater surface-to-volume ratio of hierarchical nanostructures renders them attract considerable interest as prototypical gas sensors. In this work, a novel resistive gas sensor based on TiO2/Ag0.35V2O5 branched nanoheterostructures is fabricated by a facile one-step synthetic process and the ethanol sensing performance of this device is characterized systematically, which shows faster response/recovery behavior, better selectivity, and higher sensitivity of about 9 times as compared to the ...[more]

PMID: 27615429

Similar Datasets

Project description:Chain elongation fermentation allows for the synthesis of biobased chemicals from complex organic residue streams. To expand the product spectrum of chain elongation technology and its application range we investigated 1) how to increase selectivity towards branched chain elongation and 2) whether alternative branched carboxylates such as branched valerates can be used as electron acceptors. Elongation of isobutyrate elongation towards 4-methyl-pentanoate was achieved with a selectivity of 27% (of total products, based on carbon atoms) in a continuous system that operated under CO2 and acetate limited conditions. Increasing the CO2 load led to more in situ acetate formation that increased overall chain elongation rate but decreased the selectivity of branched chain elongation. A part of this acetate formation was related to direct ethanol oxidation that seemed to be thermodynamically coupled to hydrogenotrophic carboxylate reduction to corresponding alcohols. Several alcohols including isobutanol and n-hexanol were formed. The microbiome from the continuous reactor was also able to form small amounts of 5-methyl-hexanoate likely from 3-methyl-butanoate and ethanol as substrate in batch experiments. The highest achieved concentration of isoheptanoate was 6.4 ± 0.9 mM Carbon, or 118 ± 17 mg/L, which contributed for 7% to the total amount of products (based on carbon atoms). The formation of isoheptanoate was dependent on the isoform of branched valerate. With 3-methyl-butanoate as substrate 5-methylhexanoate was formed, whereas a racemic mixture of L/D 2-methyl-butanoate did not lead to an elongated product. When isobutyrate and isovalerate were added simultaneously as substrates there was a large preference for elongation of isobutyrate over isovalerate. Overall, this work showed that chain elongation microbiomes can be further adapted with supplement of branched-electron acceptors towards the formation of iso-caproate and iso-heptanoate as well as that longer chain alcohol formation can be stimulated.

Dataset Information

A novel ethanol gas sensor based on TiO2/Ag0.35V2O5 branched nanoheterostructures.

Publications

A novel ethanol gas sensor based on TiO2/Ag0.35V2O5 branched nanoheterostructures.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets