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Facile transformation of FeO/Fe3O4 core-shell nanocubes to Fe3O4 via magnetic stimulation.


ABSTRACT: Here, we propose the use of magnetic hyperthermia as a means to trigger the oxidation of Fe1-xO/Fe3-?O4 core-shell nanocubes to Fe3-?O4 phase. As a first relevant consequence, the specific absorption rate (SAR) of the initial core-shell nanocubes doubles after exposure to 25 cycles of alternating magnetic field stimulation. The improved SAR value was attributed to a gradual transformation of the Fe1-xO core to Fe3-?O4, as evidenced by structural analysis including high resolution electron microscopy and Rietveld analysis of X-ray diffraction patterns. The magnetically oxidized nanocubes, having large and coherent Fe3-?O4 domains, reveal high saturation magnetization and behave superparamagnetically at room temperature. In comparison, the treatment of the same starting core-shell nanocubes by commonly used thermal annealing process renders a transformation to ?-Fe2O3. In contrast to other thermal annealing processes, the method here presented has the advantage of promoting the oxidation at a macroscopic temperature below 37?°C. Using this soft oxidation process, we demonstrate that biotin-functionalized core-shell nanocubes can undergo a mild self-oxidation transformation without losing their functional molecular binding activity.

SUBMITTER: Lak A 

PROVIDER: S-EPMC5036086 | biostudies-other | 2016 Sep

REPOSITORIES: biostudies-other

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Facile transformation of FeO/Fe<sub>3</sub>O<sub>4</sub> core-shell nanocubes to Fe<sub>3</sub>O<sub>4</sub> via magnetic stimulation.

Lak Aidin A   Niculaes Dina D   Anyfantis George C GC   Bertoni Giovanni G   Barthel Markus J MJ   Marras Sergio S   Cassani Marco M   Nitti Simone S   Athanassiou Athanassia A   Giannini Cinzia C   Pellegrino Teresa T  

Scientific reports 20160926


Here, we propose the use of magnetic hyperthermia as a means to trigger the oxidation of Fe<sub>1-x</sub>O/Fe<sub>3-δ</sub>O<sub>4</sub> core-shell nanocubes to Fe<sub>3-δ</sub>O<sub>4</sub> phase. As a first relevant consequence, the specific absorption rate (SAR) of the initial core-shell nanocubes doubles after exposure to 25 cycles of alternating magnetic field stimulation. The improved SAR value was attributed to a gradual transformation of the Fe<sub>1-x</sub>O core to Fe<sub>3-δ</sub>O<su  ...[more]

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