Highly Efficient Perovskite Solar Cells with Substantial Reduction of Lead Content.

ABSTRACT: Despite organometal halide perovskite solar cells have recently exhibited a significant leap in efficiency, the Sn-based perovskite solar cells still suffer from low efficiency. Here, a series homogeneous CH3NH3Pb(1-x)SnxI3 (0???x???1) perovskite thin films with full coverage were obtained via solvent engineering. In particular, the intermediate complexes of PbI2/(SnI2)?(DMSO)x were proved to retard the crystallization of CH3NH3SnI3, thus allowing the realization of high quality Sn-introduced perovskite thin films. The external quantum efficiency (EQE) of as-prepared solar cells were demonstrated to extend a broad absorption minimum over 50% in the wavelength range from 350 to 950 nm accompanied by a noteworthy absorption onset up to 1050?nm. The CH3NH3Pb0.75Sn0.25I3 perovskite solar cells with inverted structure were consequently realized with maximum power conversion efficiency (PCE) of 14.12%.

SUBMITTER: Liu C 

PROVIDER: S-EPMC5067674 | biostudies-other | 2016 Oct

REPOSITORIES: biostudies-other