Ontology highlight
ABSTRACT:
SUBMITTER: Shu W
PROVIDER: S-EPMC5241786 | biostudies-other | 2017 Jan
REPOSITORIES: biostudies-other
Nature communications 20170113
The quest for selective C-H functionalization reactions, able to provide new strategic opportunities for the rapid assembly of molecular complexity, represents a major focus of the chemical community. Examples of non-directed, remote Csp<sup>3</sup>-H activation to forge complex carbon frameworks remain scarce due to the kinetic stability and thus intrinsic challenge associated to the chemo-, regio- and stereoselective functionalization of aliphatic C-H bonds. Here we describe a radical-mediated ...[more]