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Spectroscopic and Electrochemical Studies of Imogolite and Fe-Modified Imogolite Nanotubes.

ABSTRACT: Carbon nanotubes and other forms of carbon nanoparticles, as well as metal nanoparticles have been widely used in film electrochemistry because they allow for the immobilization of larger amounts of catalyst (either biological or inorganic) on the top of the modified electrodes. Nevertheless, those nanoparticles present high costs of synthesis and of separation and purification that hamper their employment. On the other hand, imogolites (Im), with the general formula (OH)?Al?O?SiOH, are naturally-occurring nanomaterials, which can be obtained from glassy volcanic ash soils and can also be synthesized at mild conditions. In this research paper, we characterize through spectroscopic techniques (i.e., fourier transform infrared spectroscopy (FTIR) spectroscopy, powder X-ray diffraction (XRD) and transmission electron microscopy (TEM)) synthetized Im and Fe-modified imogolite (Im(Fe)). Moreover, the Im and Im(Fe) were physically adsorbed on the top of a graphite electrode (GE) and were characterized electrochemically in the potential region ranging from -0.8 to 0.8 V vs. the saturated calomel electrode (SCE). When the film of the Im or of the Im(Fe) was present on the top of the electrode, the intensity of the charging/discharging current increased two-fold, but no redox activity in the absence of O? could be appreciated. To show that Im and Im(Fe) could be used as support for catalysts, iron phthalocyanine (FePc) was adsorbed on the top of the Im or Im(Fe) film, and the electrocatalytic activity towards the O? reduction was measured. In the presence of the Im, the measured electrocatalytic current for O? reduction increased 30%, and the overpotential drastically decreased by almost 100 mV, proving that the Im can act as a good support for the electrocatalysts.

SUBMITTER: Castro C

PROVIDER: S-EPMC5302487 | biostudies-other | 2016 Feb

REPOSITORIES: biostudies-other

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Spectroscopic and Electrochemical Studies of Imogolite and Fe-Modified Imogolite Nanotubes.

Castro Carmen C Arancibia-Miranda Nicolas N Acuña-Rougier Cristina C Escudey Mauricio M Tasca Federico F

Nanomaterials (Basel, Switzerland) 20160202 2

Carbon nanotubes and other forms of carbon nanoparticles, as well as metal nanoparticles have been widely used in film electrochemistry because they allow for the immobilization of larger amounts of catalyst (either biological or inorganic) on the top of the modified electrodes. Nevertheless, those nanoparticles present high costs of synthesis and of separation and purification that hamper their employment. On the other hand, imogolites (Im), with the general formula (OH)₃Al₂O₃SiOH, are naturall ...[more]

PMID: 28344285

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Project description:Fe/Ti-oxides-modified-carbon nanotubes CNTs nanocomposites were prepared and tested toward Co removal from solution under different operational conditions. The final performance of the nanocomposites for Co was highly dependent on the type and loaded amount of the oxides. The nanocomposites were characterized by standard methods and the results evidenced that the presence of CNTs hampers the growth of Fe3O4 and TiO2 particles and forming smaller nano-particles leading to better Co removal from solution. Analysis of isotherms at different temperatures indicated that Co retention was two-fold increased upon adding Ti-oxides up to 90.2%. All isotherms were fairly presented using Langmuir-Freundlich isotherm and most surfaces have high heterogeneity particularly after deposition of oxides. The combined influence of the factors was investigated by running a multivariate analysis. An empirical equation was generated by principal component analysis (PCA) for predicting Co retention assuming different relationships and the binary-interaction behavior between factors was the most dominant: Co retention (mg/g) = 5.12 + 1.25Conc + 1.47Temp - 1.38CNT% - 6.03Ti% - 5.03Fe% - 0.01Conc2 + 0.12Temp2 - 0.55CNT%2 - 1.53Ti%2 - 3.44Fe%2 + 0.17Conc × Temp + 0.07Conc × CNT% + 0.07Conc × Ti% + 0.10Conc × Fe% + 0.21Temp × CNT% + 0.10Temp × Ti% + 0.17Temp × Fe% - 1.67CNT% × Ti% - 1.45CNT% × Fe% - 4.11Ti% × Fe%. The most dominant factors on Co retention were temperature and concentration (positive linear correlation) and the positive interaction between temperature/concentration and temperature/CNTs mass. PCA indicated that the coefficient Temp × CNTs (+0.21) was higher than Temp × Ti% (+0.10). The negative coefficients of Ti/Fe with CNTs (1.45-4.11) indicated better Co retention at higher Ti/Fe loads and lower mass of CNTs. The results support that fact that incorporation of CNTs with Ti/Fe oxides may have a positive synergic impact on Co retention.

Dataset Information

Spectroscopic and Electrochemical Studies of Imogolite and Fe-Modified Imogolite Nanotubes.

Publications

Spectroscopic and Electrochemical Studies of Imogolite and Fe-Modified Imogolite Nanotubes.

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