Ontology highlight
ABSTRACT:
SUBMITTER: Rice AM
PROVIDER: S-EPMC5396291 | biostudies-other | 2017 Apr
REPOSITORIES: biostudies-other
Rice Allison M AM Fellows W Brett WB Dolgopolova Ekaterina A EA Greytak Andrew B AB Vannucci Aaron K AK Smith Mark D MD Karakalos Stavros G SG Krause Jeanette A JA Avdoshenko Stanislav M SM Popov Alexey A AA Shustova Natalia B NB
Angewandte Chemie (International ed. in English) 20170323 16
We report the first example of a donor-acceptor corannulene-containing hybrid material with rapid ligand-to-ligand energy transfer (ET). Additionally, we provide the first time-resolved photoluminescence (PL) data for any corannulene-based compounds in the solid state. Comprehensive analysis of PL data in combination with theoretical calculations of donor-acceptor exciton coupling was employed to estimate ET rate and efficiency in the prepared material. The ligand-to-ligand ET rate calculated us ...[more]