Ontology highlight
ABSTRACT:
SUBMITTER: Shao A
PROVIDER: S-EPMC5407263 | biostudies-other | 2017 Mar
REPOSITORIES: biostudies-other
Chemical science 20161207 3
Selective carbon-carbon and carbon-heteroatom bond cleavage was achieved in a one reaction system. With this strategy a novel Pd/Cu-catalyzed aerobic oxidative oxosulfonation of olefins with DMSO has been developed. Preliminary mechanistic investigations indicated that CO/O<sub>2</sub> assisted the bond cleavage and the leaving groups from the starting materials were trapped by O<sub>2</sub> and underwent a hydroxylation process. ...[more]