Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Carbon Derived from Jatropha Seed Hull as a Potential Green Adsorbent for Cadmium (II) Removal from Wastewater.

ABSTRACT: Carbon from jatropha seed hull (JC) was prepared to study the adsorption of cadmium ions (Cd2+) from aqueous solutions under various experimental conditions. Batch equilibrium methods have been used to study the influences of the initial metal ion concentration (0.5-50 ppm), dosage (0.2-1 g), contact time (0-300 min), pH (2-7), and temperature (26-60 °C) on adsorption behavior. It has been found that the amount of cadmium adsorbed increases with the initial metal ion concentration, temperature, pH, contact time, and amount of adsorbent. A kinetic study proved that the mechanism of Cd2+ adsorption on JC followed a three steps process, confirmed by an intraparticle diffusion model: rapid adsorption of metal ions, a transition phase, and nearly flat plateau section. The experimental results also showed that the Cd2+ adsorption process followed pseudo-second-order kinetics. The Langmuir and Freundlich adsorption isotherm models were used to describe the experimental data, with the former exhibiting a better correlation coefficient than the latter (R² = 0.999). The monolayer adsorption capacity of JC has been compared with the capacities of the other reported agriculturally-based adsorbents. It has been clearly demonstrated that this agricultural waste generated by the biofuel industry can be considered a potential low-cost adsorbent for the removal of Cd2+ from industrial effluents.

SUBMITTER: Mohammad M

PROVIDER: S-EPMC5452857 | biostudies-other | 2013 Oct

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Similar Datasets

Green-synthesized copper nano-adsorbent for the removal of pharmaceutical pollutants from real wastewater samples.

Project description:The release of Non-Steroidal Anti-Inflammatory drugs (NSAIDs) such as Ibuprofen (Ibu), Naproxen (Nab) and Diclofenac (Dic) to the aquatic system cause serious environmental problems. In this study, green-synthesized copper nanoparticles (Cu NPs) have been used as nano-adsorbent for the removal of Ibu, Nab, and Dic from wastewater samples. Formation of Cu NPs was confirmed by different analytical techniques. The adsorption parameters such as temperature, pH, adsorbate concentration, adsorbent dose and contact time were studied. The best removal results were obtained at these conditions: temperature 298 K, pH = 4.5, 10.0 mg Cu NPs, 60 min. At these conditions, the removal percentage of Ibu, Nap, and Dic were found to be 74.4, 86.9 and 91.4% respectively. The maximum monolayer adsorption capacities were calculated as 36.0, 33.9 and 33.9 mg/g for Dic, Nap, and Ibu respectively. The kinetic studies conducted that the sorption process obeyed the second order kinetic model, while the thermodynamic results revealed that the adsorption process was spontaneous, endothermic (+23.8, +40.8 and +38.3 kJ/mol for Ibu, Nap and Dic respectively). The results revealed that green-synthesized copper nano-adsorbent may be used for the removal of the anti-inflammatory drugs from real wastewater efficiently.

| S-EPMC6716349 | biostudies-literature

Development of a ZnOS+C Composite as a Potential Adsorbent for the Effective Removal of Fast Green Dye from Real Wastewater.

Project description:Wastewater treatment is becoming increasingly important due to the potential shortage of pure drinking water in many parts of the world. Adsorption offers a potential technique for the uptake of contaminants and wastewater purification. In the last two decades, several efforts have been made to remove fast green (FG) dye from wastewater via different adsorbent materials. However, adsorption capacity shown by these adsorbents is low and time-consuming. Herein, we have synthesized for the first time a new powdered adsorbent ZnOS+C, modified zinc peroxide with sulfur and activated carbon to effectively remove FG dye from wastewater. Results of batch adsorption experiments have suggested that ZnOS+C has the maximum adsorption potential of 238.28 mg/g for FG dye within 120 min of adsorption equilibrium for a wide range of pH ranging from 2 to 10 pH. The adsorption process conforms to the Freundlich isotherm model, suggesting a multilayered adsorption process on the outer surface of ZnOS+C. The adsorption kinetics study indicates that the kinetics of the reaction are the intraparticle diffusion model. Briefly, this study shows proof of the application of ZnOS+C powder as a new eco-friendly adsorbent with extremely high efficiency and high surface area for removing FG dye.

| S-EPMC10018503 | biostudies-literature

A Magnetic Adsorbent for the Removal of Cationic Dyes from Wastewater.

Project description:In this article, a study was presented on the adsorption activity of a new nanocomposite particle Fe₃O₄@1, which was synthesized by combining [Cu(HL)₂]₂H₂[P₂Mo₅O23]·10H₂O (1) (HL = 2-acetylpyridine semicarbazone) and Fe₃O₄ nanoparticles. Transmission electron microscopy and X-ray powder diffraction analyses revealed that Fe₃O₄@1 possessed high crystallinity with an average particle size of 19.1 nm. The adsorption activity of the as-prepared Fe₃O₄@1 was investigated by photometrically monitoring the removal of methylene blue, rhodamine B, safranine T, gentian violet, fuchsin basic, and methyl orange from aqueous solutions. Significantly, we could easily separate Fe₃O₄@1 from the reaction media by applying an external magnet. Furthermore, the recycling performance was observed using methylene blue, revealing the recyclability and high stability of Fe₃O₄@1. It was shown that Fe₃O₄@1 is a promising candidate material for adsorbing cationic dyes in aqueous media.

| S-EPMC6163381 | biostudies-literature

Synthesis of adsorbent from Tamarix hispida and modified by lanthanum metal for fluoride ions removal from wastewater: Adsorbent characteristics and real wastewater treatment data.

Project description:This data article describes a facile method for production of an adsorbent from Tamarix hispida wasted wood and modified by lanthanum metal for fluoride ions removal from wastewater. The main characteristics of the adsorbent consist of BET surface area, functional groups, and elemental analysis is presented. The data for attenuating the pollutants from a real wastewater treatment which was provided from a glass factory is also represented. More than 90% of fluoride content of the real wastewater was treated by the adsorbent. Generally, these data would be informative for extend research aim to industrial wastewater treatment and those who work in the wastewater treatment plants.

| S-EPMC5575414 | biostudies-literature

Defective Bismuth Oxide as Effective Adsorbent for Arsenic Removal from Water and Wastewater.

Project description:In this work, we report solid-state synthetized defective Bi2O3 containing Bi(V) sites as effective and recyclable arsenic adsorbent materials. Bi2O3 was extensively characterized, and structure-related adsorption processes are reported. Both As(V) and As(III) species-adsorption processes were investigated in a wide range of concentrations, pH values, and times. The effect of several competing ions was also tested together with the adsorbent recyclability.

| S-EPMC8309858 | biostudies-literature

Layered zinc hydroxide as an adsorbent for phosphate removal and recovery from wastewater.

Project description:At present, phosphate removal and recovery from wastewater is gaining wide attention due to the dual issues of eutrophication, caused by the increased production of algae, and universal phosphorus scarcity. In this study, a layered zinc hydroxide (LZH) was synthesized by a simple precipitation method and characterized via various techniques. Experiments investigating the effect of contact time, pH, LZH dose, initial phosphate concentration, and co-existing ions on phosphate adsorption were conducted. LZH exhibited a high phosphate adsorption capacity (135.4 mg g-1) at a neutral pH. More than 50% of phosphate was removed within the first 60 s of contact time at an initial phosphate concentration of 5 mg L-1. Phosphate removal using the as-prepared LZH adsorbent was also tested in real treated sewage effluent reducing the residual phosphate amount to levels inhibiting to the growth of algae. Furthermore, phosphate desorption from LZH was investigated using acetic acid and sodium hydroxide regenerants which showed to be very effective for phosphate recovery.

| S-EPMC9040826 | biostudies-literature

Biological nitrogen removal from low carbon wastewater

Project description:Nitrogen has traditionally been removed from wastewater by nitrification and denitrification processes, in which organic carbon has been used as an electron donor during denitrification. However, some wastewaters contain low concentrations of organic carbon, which may require external organic carbon supply, increasing treatment costs. As a result, processes such as partial nitrification/anammox (anaerobic ammonium oxidation) (PN/A), autotrophic denitrification, nitritation-denitritation and bioelectrochemical processes have been studied as possible alternatives, and are thus evaluated in this study based on process kinetics, applicability at large-scale and process configuration. Oxygen demand for nitritation-denitritation and PN/A is 25% and 60% lower than for nitrification/denitrification, respectively. In addition, PN/A process does not require organic carbon supply, while its supply for nitritation-denitritation is 40% less than for nitrification/denitrification. Both PN/A and nitritation-denitritation produce less sludge compared to nitrification/denitrification, which saves on sludge handling costs. Similarly, autotrophic denitrification generates less sludge compared to heterotrophic denitrification and could save on sludge handling costs. However, autotrophic denitrification driven by metallic ions, elemental sulfur (S) and its compounds could generate harmful chemicals. On the other hand, hydrogenotrophic denitrification can remove nitrogen completely without generation of harmful chemicals, but requires specialized equipment for generation and handling of hydrogen gas (H2), which complicates process configuration. Bioelectrochemical processes are limited by low kinetics and complicated process configuration. In sum, anammox-mediated processes represent the best alternative to nitrification/denitrification for nitrogen removal in low- and high-strength wastewaters.

| S-EPMC9709150 | biostudies-literature

Activated carbon derived from <i>Azolla filiculoides</i> fern: a high-adsorption-capacity adsorbent for residual ampicillin in pharmaceutical wastewater.

Project description:In this study, the effectiveness of activated carbon prepared from the Azolla filiculoides fern (ACAF) in order to remove ampicillin from aqueous solution was examined. The preparation of the ACAF was performed through chemical and physical activation processes with the presence of ZnCl2 and at a temperature of 450 °C. The ACAF yield was 44.7% of the fresh Azolla filiculoides. The results obtained from the characterization study indicate that the prepared ACAF has excellent surface and internal properties to be used as an adsorbent. The surface area, porosity, and pore volume were estimated to be 716.4 m2/g, 51.2%, and 0.621 cm3/g, respectively. The functional groups in ACAF that were responsible for the adsorption of ampicillin molecules were detected using FTIR analyses. The maximum efficiency (96.84%) and uptake (114.3 mg/g) of ACAF to remove ampicillin were achieved under the following conditions: ACAF dose = 0.8 g/L, pH = 7, concentration of ampicillin = 100 mg/L, contact time = 60 min, and temperature = 45 °C. It was found that the kinetic and isotherm data matched the pseudo-second-order and Langmuir models with high precision values, respectively. Considering the thermodynamics of the adsorption, the endothermic and spontaneous nature of the ampicillin adsorption onto ACAF was approved. The ampicillin adsorption capacity by ACAF was not significantly affected by the presence of different concentrations of NaNO3 competitor ion. The considerably higher adsorption capacity of the ACAF for ampicillin (114.3 mg/g) than other previously used adsorbents with excellent regeneration level (five cycles) depicts the superior performance of ACAF in the adsorption systems.Supplementary informationThe online version contains supplementary material available at 10.1007/s13399-021-01962-4.

| S-EPMC8487454 | biostudies-literature

ZnO@ activated carbon derived from wood sawdust as adsorbent for removal of methyl red and methyl orange from aqueous solutions.

Project description:Activated carbon (AC) and ZnO@AC composite derived from wood sawdust were prepared to be utilized as adsorbents for methyl red (MR) and methyl orange (MO) anionic dyes from the aqueous solutions. The maximum adsorption capacity of the AC and ZnO@AC composite toward both dyes was achieved in the strong acidic medium (pH = 3), and under stirring for 60 min. The kinetic studies revealed that the adsorption of MR and MO dyes onto the AC and ZnO@AC composite fitted well with the pseudo-second-order model. Furthermore, the intraparticle diffusion and Elovich kinetic models confirmed the adsorption is controlled by external surfaces, and the adsorption is chemisorption process. The isotherm results indicated that the MR and MO dye adsorption occurred via monolayer adsorption, and the estimated maximum adsorption capacities of both dyes onto the ZnO@AC composite were higher than those achieved by AC. Thermodynamic analysis suggested that the adsorption is endothermic and spontaneous. The mechanism for MR, and MO dyes adsorption onto the AC and ZnO@AC composite is proposed to be controlled by electrostatic bonding, π-π interactions, and ion exchange, while H-bonding and n-π interactions were minor contributors. This study reveals the potential use of carbon-based adsorbents derived from wood sawdust for the removal of anionic dyes from wastewater.

| S-EPMC10915167 | biostudies-literature

Polypyrrole-Grafted Coconut Shell Biological Carbon as a Potential Adsorbent for Methyl Tert-Butyl Ether Removal: Characterization and Adsorption Capability.

Project description:Methyl tert-butyl ether (MTBE) has been used as a common gasoline additive worldwide since the late twentieth century, and it has become the most frequently detected groundwater pollutant in many countries. This study aimed to synthesize a novel microbial carrier to improve its adsorptive capacity for MTBE and biofilm formation, compared to the traditional granular activated carbon (GAC). A polypyrrole (PPy)-modified GAC composite (PPy/GAC) was synthesized, and characterized by Fourier transform infrared spectroscopy (FT-IR) and Brunauer-Emmett-Teller (BET) surface area analysis. The adsorption behaviors of MTBE were well described by the pseudo-second-order and Langmuir isotherm models. Furthermore, three biofilm reactors were established with PPy/GAC, PPy, and GAC as the carriers, respectively, and the degradation of MTBE under continuous flow was investigated. Compared to the biofilm reactors with PPy or GAC (which both broke after a period of operation), the PPy/GAC biofilm column produced stable effluents under variable treatment conditions with a long-term effluent MTBE concentration <20 μg/L. Pseudomonas aeruginosa and Acinetobacter pittii may be the predominant bacteria responsible for MTBE degradation in these biofilm reactors.

| S-EPMC5334667 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data