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Optically Isotropic, Colorless, and Flexible PITEs/TiO2 and ZrO2 Hybrid Films with Tunable Refractive Index, Abbe Number, and Memory Properties.

ABSTRACT: A series of novel polyimidothioethers (PITEs) and the respective polymer hybrids of titania or zirconia with fantastic thermal stability and optical properties have been successfully prepared. These colorless PITEs with high transparency were synthesized by Michael polyaddition from commercially available dithiol and bismaleimides monomers. The PITE with sulfide and hydroxyl groups (S-OH) and the corresponding hybrid films declare ultra-lowest birefringence value of 0.002 and tunable refractive index (1.65-1.81 for S-OH/titania and 1.65-1.80 for S-OH/zirconia), implying large potential to the optical applications in the future. Moreover, the S-OH/zirconia hybrid films exhibit higher Abbe's number and optical transparency than those of S-OH/titania system because larger energy band gap of ZrO2. Furthermore, by adding titania and zirconia as electron acceptor into S-OH system, the charge transfer complex can be facilitated and stabilized caused by the lower LUMO energy level of hybrid materials. Consequently, the devices of memory prepared from these polymer films of hybrid showed interesting and adjustable memory behavior from DRAM, SRAM, to WORM at various titania or zirconia contents with a large ON/OFF ratio (108), denoting that the memory devices derived from these highly transparent novel S-OH/TiO2 and S-OH/ZrO2 hybrid films are attractive for the electrical applications.

SUBMITTER: Huang TT

PROVIDER: S-EPMC5554255 | biostudies-other | 2017 Aug

REPOSITORIES: biostudies-other

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Optically Isotropic, Colorless, and Flexible PITEs/TiO<sub>2</sub> and ZrO<sub>2</sub> Hybrid Films with Tunable Refractive Index, Abbe Number, and Memory Properties.

Huang Tzu-Tien TT Cheng Shun-Wen SW Tsai Chia-Liang CL Liou Guey-Sheng GS

Scientific reports 20170811 1

A series of novel polyimidothioethers (PITEs) and the respective polymer hybrids of titania or zirconia with fantastic thermal stability and optical properties have been successfully prepared. These colorless PITEs with high transparency were synthesized by Michael polyaddition from commercially available dithiol and bismaleimides monomers. The PITE with sulfide and hydroxyl groups (S-OH) and the corresponding hybrid films declare ultra-lowest birefringence value of 0.002 and tunable refractive ...[more]

PMID: 28801618

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Project description:Optical materials with high refractive index (n) have been rapidly improved because of urgent demands imposed by the development of advanced photonic and electronic devices such as solar cells, light emitting diodes (LED and Organic LED), optical lenses and filters, anti-reflection films, and optical adhesives. One successful method to obtain high refractive index materials is the blending of metal oxide nanoparticles such as TiO? and ZrO? with high n values of 2.1-2.7 into conventional polymers. However, these nanoparticles have a tendency to agglomerate by themselves in a conventional polymer matrix, due to the strong attractive forces between them. Therefore, there is a limitation in the blending amount of inorganic nanoparticles. In this paper, various hydrophilic polymers such as poly(N-hydroxyl acrylamide) (pHEAAm), poly(vinyl alcohol), poly(ethylene glycol), and poly(acrylic acid) were examined for preparation of high refractive index film based on titanium oxide nanoparticle (TiNP) dispersed polymer composite. The hydrogen bonding sites in these hydrophilic polymers would improve the dispersibility of inorganic nanoparticles in the polymer matrix. As a result, pHEAAm exhibited higher compatibility with titanium oxide nanoparticles (TiNPs) than other water-soluble polymers. Transparent hybrid films were prepared by mixing pHEAAm with TiNPs and drop casting the mixture onto a glass plate. The refractive indices of the films were in good agreement with calculated values. The compatibility of TiNPs with pHEAAm was dependent on the surface characteristics of TiNPs. TiNPs with the highest observed compatibility could be hybridized with pHEAAm at concentrations of up to 90 wt%, and the refractive index of the corresponding film reached 1.90. The high compatibility of TiNPs with pHEAAm may be related to the hydrophilicity and amide and hydroxyl moieties of pHEAAm, which cause hydrogen bond formation on the TiO? surface. The obtained thin film was slightly yellow due to the color of the original TiNP dispersion; however, the transmittance of the film was higher than 80% in the wavelength range from 480 to 900 nm.

Dataset Information

Optically Isotropic, Colorless, and Flexible PITEs/TiO2 and ZrO2 Hybrid Films with Tunable Refractive Index, Abbe Number, and Memory Properties.

Publications

Optically Isotropic, Colorless, and Flexible PITEs/TiO<sub>2</sub> and ZrO<sub>2</sub> Hybrid Films with Tunable Refractive Index, Abbe Number, and Memory Properties.

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