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Tris(?2-methano-lato)-?3-oxido-tris-{[(E)-4-chloro-2-({[2-(pyridin-2-yl)eth-yl]imino}-meth-yl)pheno-lato]manganese(III)} perchlorate-di-chloro-methane-diethyl ether (1/1.1/0.9).

ABSTRACT: In the title compound, [Mn3(C14H12ClN2O)3(CH3O)3O]ClO4·1.1CH2Cl2·0.9C4H10O, the cation consists of a central Mn3O core with ?2-methano-late bridging between adjacent MnIII atoms, thus giving each MnIII atom a mer-O3 coordination environment. Six-coordination for each MnIII atom is provided by the deprotonated Schiff base ligand (E)-4-chloro-2-({[2-(pyridin-2-yl)eth-yl]imino}-meth-yl)phenolate. There are extensive C-H?O and C-H?Cl inter-actions, which link the cations, anions, and solvent mol-ecules into a three-dimensional array.

SUBMITTER: Egekenze R

PROVIDER: S-EPMC5598829 | biostudies-other | 2017 Jul

REPOSITORIES: biostudies-other

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Tris(μ2-methano-lato)-μ3-oxido-tris-{[(E)-4-chloro-2-({[2-(pyridin-2-yl)eth-yl]imino}-meth-yl)pheno-lato]manganese(III)} perchlorate-di-chloro-methane-diethyl ether (1/1.1/0.9).

Egekenze Rita R Gultneh Yilma Y Butcher Ray J RJ

Acta crystallographica. Section E, Crystallographic communications 20170704 Pt 8

In the title compound, [Mn3(C14H12ClN2O)3(CH3O)3O]ClO4·1.1CH2Cl2·0.9C4H10O, the cation consists of a central Mn3O core with μ2-methano-late bridging between adjacent MnIII atoms, thus giving each MnIII atom a mer-O3 coordination environment. Six-coordination for each MnIII atom is provided by t ...[more]

PMID: 28932417

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