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Crystal structure of unsymmetrical ?-di-imine palladium(II) complex cis-[{ArN=C(Me)-(Et)C=NAr}PdCl2] [Ar = 2,6-(iPr)2C6H3].

ABSTRACT: The unsymmetrical ?-di-imine ligand N-{2-[2,6-bis-(propan-2-yl)phenylimino]pentan-3-yl-idene}-2,6-bis-(propan-2-yl)aniline, [ArN=C(Me)-(Et)C=NAr] [Ar = 2,6-(iPr)2C6H3], (I), and the corresponding palladium complex, cis-(N-{2-[2,6-bis-(propan-2-yl)phenylimino]pentan-3-yl-idene}-2,6-bis-(propan-2-yl)aniline)di-chlor-ido-palladium(II) 1,2-di-chloro-ethane monosolvate, [PdCl2(C29H42N2)]·C2H4Cl2 or cis[PdCl2{I}], (II), have been synthesized and characterized. The crystal and mol-ecular structure of the palladium(II) complex have been established by single-crystal X-ray diffraction. The compound crystallized along with a 1,2-di-chloro-ethane solvent of crystallization. The coordination plane of the PdII atom shows a slight tetra-hedral distortion from square-planar, as indicated by the dihedral angle between the PdCl2 and PdN2 planes of 4.19?(8)°. The chelate ring is folded along the N?N vector by 7.1?(1)°.

SUBMITTER: Ellandula SK 

PROVIDER: S-EPMC5598837 | biostudies-other | 2017 Jul

REPOSITORIES: biostudies-other

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Crystal structure of unsymmetrical α-di-imine palladium(II) complex <i>cis</i>-[{ArN=C(Me)-(Et)C=NAr}PdCl<sub>2</sub>] [Ar = 2,6-(iPr)<sub>2</sub>C<sub>6</sub>H<sub>3</sub>].

Ellandula Shravan Kumar SK   Opoku Amoako Cosmos C   Mague Joel T JT   Chandrasekaran Perumalreddy P  

Acta crystallographica. Section E, Crystallographic communications 20170707 Pt 8

The unsymmetrical α-di-imine ligand <i>N</i>-{2-[2,6-bis-(propan-2-yl)phenylimino]pentan-3-yl-idene}-2,6-bis-(propan-2-yl)aniline, [ArN=C(Me)-(Et)C=NAr] [Ar = 2,6-(iPr)<sub>2</sub>C<sub>6</sub>H<sub>3</sub>], (I), and the corresponding palladium complex, <i>cis</i>-(<i>N</i>-{2-[2,6-bis-(propan-2-yl)phenylimino]pentan-3-yl-idene}-2,6-bis-(propan-2-yl)aniline)di-chlor-ido-palladium(II) 1,2-di-chloro-ethane monosolvate, [PdCl<sub>2</sub>(C<sub>29</sub>H<sub>42</sub>N<sub>2</sub>)]·C<sub>2</sub>H<s  ...[more]

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