Ontology highlight
ABSTRACT:
SUBMITTER: Jin J
PROVIDER: S-EPMC5627188 | biostudies-other | 2017 Sep
REPOSITORIES: biostudies-other
Jin Jiaye J Li Wei W Liu Yuhong Y Wang Guanjun G Zhou Mingfei M
Chemical science 20170717 9
The cation complexes [ArB<sub>3</sub>O<sub>4</sub>]<sup>+</sup>, [ArB<sub>3</sub>O<sub>5</sub>]<sup>+</sup>, [ArB<sub>4</sub>O<sub>6</sub>]<sup>+</sup> and [ArB<sub>5</sub>O<sub>7</sub>]<sup>+</sup> were prepared <i>via</i> a laser vaporization supersonic ion source in the gas phase. Their vibrational spectra were measured <i>via</i> mass-selected infrared photodissociation spectroscopy. Spectroscopy combined with quantum chemical calculations revealed that the [ArB<sub>3</sub>O<sub>5</sub>]<sup ...[more]