Dataset Information
Observation of Contrary Thermo-responsive Trend for Single Crystal and Powder Samples in Mechano-, Thermo- and Solvato-responsive Luminescent Cubane [Ag4I4L4] Cluster.
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ABSTRACT:
SUBMITTER: Li SL
PROVIDER: S-EPMC5638816 | biostudies-other | 2017 Oct
REPOSITORIES: biostudies-other
Publications
Observation of Contrary Thermo-responsive Trend for Single Crystal and Powder Samples in Mechano-, Thermo- and Solvato-responsive Luminescent Cubane [Ag<sub>4</sub>I<sub>4</sub>L<sub>4</sub>] Cluster.
Scientific reports 20171012 1
A new silver(I) iodide cluster [Ag<sub>4</sub>I<sub>4</sub>(TMP)<sub>4</sub>] (TMP = tris(3-methylphenyl)-phosphine) 1 shows triply stimuli-responsive luminescent chromism, namely, mechano-, thermo- and solvent-responsive chromism, which is isostructural to our previously reported [Cu<sub>4</sub>I<sub>4</sub>(TMP)<sub>4</sub>] 2 but shows quite different luminescence in response to the external stimuli. Especially, during the mechanical grinding, the relative intensities of HE and LE of 1 varied ...[more]