Browse
Submit Data
Databases
API
Help

Dataset Information

14 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Carbon dioxide capture and conversion by an acid-base resistant metal-organic framework.

ABSTRACT: Considering the rapid increase of CO2 emission, especially from power plants, there is a constant need for materials which can effectively eliminate post-combustion CO2 (the main component: CO2/N2?=?15/85). Here, we show the design and synthesis of a Cu(II) metal-organic framework (FJI-H14) with a high density of active sites, which displays unusual acid and base stability and high volumetric uptake (171?cm3?cm-3) of CO2 under ambient conditions (298?K, 1?atm), making it a potential adsorbing agent for post-combustion CO2. Moreover, CO2 from simulated post-combustion flue gas can be smoothly converted into corresponding cyclic carbonates by the FJI-H14 catalyst. Such high CO2 adsorption capacity and moderate catalytic activity may result from the synergistic effect of multiple active sites.

SUBMITTER: Liang L

PROVIDER: S-EPMC5663901 | biostudies-other | 2017 Nov

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Carbon dioxide capture and conversion by an acid-base resistant metal-organic framework.

Liang Linfeng L Liu Caiping C Jiang Feilong F Chen Qihui Q Zhang Linjie L Xue Hui H Jiang Hai-Long HL Qian Jinjie J Yuan Daqiang D Hong Maochun M

Nature communications 20171101 1

Considering the rapid increase of CO2 emission, especially from power plants, there is a constant need for materials which can effectively eliminate post-combustion CO2 (the main component: CO2/N2 = 15/85). Here, we show the design and synthesis of a Cu(II) metal-organic framework (FJI-H14) with a high density of active sites, which displays unusual acid and base stability and high volumetric uptake (171 cm3 cm-3) of CO2</sub ...[more]

PMID: 29089480

Similar Datasets

Selective capture of carbon dioxide from hydrocarbons using a metal-organic framework.

Project description:Efficient and sustainable methods for carbon dioxide capture are highly sought after. Mature technologies involve chemical reactions that absorb CO2, but they have many drawbacks. Energy-efficient alternatives may be realised by porous physisorbents with void spaces that are complementary in size and electrostatic potential to molecular CO2. Here, we present a robust, recyclable and inexpensive adsorbent termed MUF-16. This metal-organic framework captures CO2 with a high affinity in its one-dimensional channels, as determined by adsorption isotherms, X-ray crystallography and density-functional theory calculations. Its low affinity for other competing gases delivers high selectivity for the adsorption of CO2 over methane, acetylene, ethylene, ethane, propylene and propane. For equimolar mixtures of CO2/CH4 and CO2/C2H2, the selectivity is 6690 and 510, respectively. Breakthrough gas separations under dynamic conditions benefit from short time lags in the elution of the weakly-adsorbed component to deliver high-purity hydrocarbon products, including pure methane and acetylene.

| S-EPMC7794324 | biostudies-literature

A cofacial metal-organic framework based photocathode for carbon dioxide reduction.

Project description:Innovative and robust photosensitisation materials play a cardinal role in advancing the combined effort towards efficient solar energy harvesting. Here, we demonstrate the photocathode functionality of a Metal-Organic Framework (MOF) featuring cofacial pairs of photo- and electro-active 1,4,5,8-naphthalenediimide (NDI) ligands, which was successfully applied to markedly reduce the overpotential required for CO2 reduction to CO by a well-known rhenium molecular electrocatalyst. Reduction of [Cd(DPNDI)(TDC)] n (DPNDI = N,N'-di(4-pyridyl)-1,4,5,8-naphthalenediimide, H2TDC = thiophene-2,5-dicarboxylic acid) to its mixed-valence state induces through-space Intervalence Charge Transfer (IVCT) within cofacial DPNDI units. Irradiation of the mixed-valence MOF in the visible region generates a DPNDI photoexcited radical monoanion state, which is stabilised as a persistent species by the inherent IVCT interactions and has been rationalised using Density Functional Theory (DFT). This photoexcited radical monoanion state was able to undergo charge transfer (CT) reduction of the rhenium molecular electrocatalyst to effect CO generation at a lower overpotential than that required by the discrete electrocatalyst itself. The exploitation of cofacial MOFs opens new directions for the design philosophy behind light harvesting materials.

| S-EPMC8179387 | biostudies-literature

Base-Resistant Ionic Metal-Organic Framework as a Porous Ion-Exchange Sorbent.

Project description:A systematic approach has been employed to obtain a hydrolytically stable cationic metal-organic framework (MOF). The synthesized two-dimensional Ni(II)-centered cationic MOF, having its backbone built from purely neutral N-donor ligand, is found to exhibit uncommon resistance over wide pH range, particularly even under highly alkaline conditions. This report presents a rare case of a porous MOF retaining structural integrity under basic conditions, and an even rarer case of a porous cationic MOF. The features of stability and porosity in this ionic MOF have been harnessed for the function of charge- and size-selective capture of small organic dye through ion-exchange process across a wide pH range.

| S-EPMC6137287 | biostudies-literature

Crystal-Size Effects on Carbon Dioxide Capture of a Covalently Alkylamine-Tethered Metal-Organic Framework Constructed by a One-Step Self-Assembly.

Project description:To enhance the carbon dioxide (CO2) uptake of metal-organic frameworks (MOFs), amine functionalization of their pore surfaces has been studied extensively. In general, amine-functionalized MOFs have been synthesized via post-synthetic modifications. Herein, we introduce a one-step construction of a MOF ([(NiLethylamine)(BPDC)] = MOFNH2; [NiLethylamine](2+) = [Ni(C12H32N8)](2+); BPDC(2-) = 4,4'-biphenyldicarboxylate) possessing covalently tethered alkylamine groups without post-synthetic modification. Two-amine groups per metal centre were introduced by this method. MOFNH2 showed enhanced CO2 uptake at elevated temperatures, attributed to active chemical interactions between the amine groups and the CO2 molecules. Due to the narrow channels of MOFNH2, the accessibility to the channel of CO2 is the limiting factor in its sorption behaviour. In this context, only crystal size reduction of MOFNH2 led to much faster and greater CO2 uptake at low pressures.

| S-EPMC4725930 | biostudies-literature

Made-to-order metal-organic frameworks for trace carbon dioxide removal and air capture.

Project description:Direct air capture is regarded as a plausible alternate approach that, if economically practical, can mitigate the increasing carbon dioxide emissions associated with two of the main carbon polluting sources, namely stationary power plants and transportation. Here we show that metal-organic framework crystal chemistry permits the construction of an isostructural metal-organic framework (SIFSIX-3-Cu) based on pyrazine/copper(II) two-dimensional periodic 4(4) square grids pillared by silicon hexafluoride anions and thus allows further contraction of the pore system to 3.5 versus 3.84 Å for the parent zinc(II) derivative. This enhances the adsorption energetics and subsequently displays carbon dioxide uptake and selectivity at very low partial pressures relevant to air capture and trace carbon dioxide removal. The resultant SIFSIX-3-Cu exhibits uniformly distributed adsorption energetics and offers enhanced carbon dioxide physical adsorption properties, uptake and selectivity in highly diluted gas streams, a performance, to the best of our knowledge, unachievable with other classes of porous materials.

| S-EPMC4083436 | biostudies-other

Unravelling exceptional acetylene and carbon dioxide adsorption within a tetra-amide functionalized metal-organic framework.

Project description:Understanding the mechanism of gas-sorbent interactions is of fundamental importance for the design of improved gas storage materials. Here we report the binding domains of carbon dioxide and acetylene in a tetra-amide functionalized metal-organic framework, MFM-188, at crystallographic resolution. Although exhibiting moderate porosity, desolvated MFM-188a exhibits exceptionally high carbon dioxide and acetylene adsorption uptakes with the latter (232?cm3?g-1 at 295?K and 1?bar) being the highest value observed for porous solids under these conditions to the best of our knowledge. Neutron diffraction and inelastic neutron scattering studies enable the direct observation of the role of amide groups in substrate binding, representing an example of probing gas-amide binding interactions by such experiments. This study reveals that the combination of polyamide groups, open metal sites, appropriate pore geometry and cooperative binding between guest molecules is responsible for the high uptakes of acetylene and carbon dioxide in MFM-188a.

| S-EPMC5309720 | biostudies-literature

Active Nanointerfaces Based on Enzyme Carbonic Anhydrase and Metal-Organic Framework for Carbon Dioxide Reduction.

Project description:Carbonic anhydrases are enzymes capable of transforming carbon dioxide into bicarbonate to maintain functionality of biological systems. Synthetic isolation and implementation of carbonic anhydrases into membrane have recently raised hopes for emerging and efficient strategies that could reduce greenhouse emission and the footprint of anthropogenic activities. However, implementation of such enzymes is currently challenged by the resulting membrane's wetting capability, overall membrane performance for gas sensing, adsorption and transformation, and by the low solubility of carbon dioxide in water, the required medium for enzyme functionality. We developed the next generation of enzyme-based interfaces capable to efficiently adsorb and reduce carbon dioxide at room temperature. For this, we integrated carbonic anhydrase with a hydrophilic, user-synthesized metal-organic framework; we showed how the framework's porosity and controlled morphology contribute to viable enzyme binding to create functional surfaces for the adsorption and reduction of carbon dioxide. Our analysis based on electron and atomic microscopy, infrared spectroscopy, and colorimetric assays demonstrated the functionality of such interfaces, while Brunauer-Emmett-Teller analysis and gas chromatography analysis allowed additional evaluation of the efficiency of carbon dioxide adsorption and reduction. Our study is expected to impact the design and development of active interfaces based on enzymes to be used as green approaches for carbon dioxide transformation and mitigation of global anthropogenic activities.

| S-EPMC8071118 | biostudies-literature

Modulating supramolecular binding of carbon dioxide in a redox-active porous metal-organic framework.

Project description:Hydrogen bonds dominate many chemical and biological processes, and chemical modification enables control and modulation of host-guest systems. Here we report a targeted modification of hydrogen bonding and its effect on guest binding in redox-active materials. MFM-300(VIII) {[VIII2(OH)2(L)], LH4=biphenyl-3,3',5,5'-tetracarboxylic acid} can be oxidized to isostructural MFM-300(VIV), [VIV2O2(L)], in which deprotonation of the bridging hydroxyl groups occurs. MFM-300(VIII) shows the second highest CO2 uptake capacity in metal-organic framework materials at 298?K and 1?bar (6.0?mmol?g-1) and involves hydrogen bonding between the OH group of the host and the O-donor of CO2, which binds in an end-on manner, =1.863(1)?Å. In contrast, CO2-loaded MFM-300(VIV) shows CO2 bound side-on to the oxy group and sandwiched between two phenyl groups involving a unique ···c.g.phenyl interaction [3.069(2), 3.146(3) Å]. The macroscopic packing of CO2 in the pores is directly influenced by these primary binding sites.

| S-EPMC5316804 | biostudies-other

Monolithic metal-organic frameworks for carbon dioxide separation.

Project description:Carbon dioxide (CO2) is both a primary contributor to global warming and a major industrial impurity. Traditional approaches to carbon capture involve corrosive and energy-intensive processes such as liquid amine absorption. Although adsorptive separation has long been a promising alternative to traditional processes, up to this point there has been a lack of appropriate adsorbents capable of capturing CO2 whilst maintaining low regeneration energies. In the context of CO2 capture, metal-organic frameworks (MOFs) have gained much attention in the past two decades as potential materials. Their tuneable nature allows for precise control over the pore size and chemistry, which allows for the tailoring of their properties for the selective adsorption of CO2. While many candidate materials exist, the amount of research into material shaping for use in industrial processes has been limited. Traditional shaping strategies such as pelletisation involve the use of binders and/or mechanical processes, which can have a detrimental impact on the adsorption properties of the resulting materials or can result in low-density structures with low volumetric adsorption capacities. Herein, we demonstrate the use of a series of monolithic MOFs (monoUiO-66, monoUiO-66-NH2 & monoHKUST-1) for use in gas separation processes.

| S-EPMC8517963 | biostudies-literature

Ethylenediamine loading into a manganese-based metal-organic framework enhances water stability and carbon dioxide uptake of the framework.

Project description:Metal-organic frameworks (MOFs) based on 2,5-dihydroxyterepthalic acid (DOBDC) as the linker show very high CO2 uptake capacities at low to moderate CO2 pressures; however, these MOFs often require expensive solvent for synthesis and are difficult to regenerate. We have synthesized a Mn-DOBDC MOF and modified it to introduce amine groups into the structure by functionalizing its metal coordination sites with ethylenediamine (EDA). Repeat framework synthesis was then also successfully performed using recycled dimethylformamide (DMF) solvent. Characterization by elemental analysis, FTIR and thermogravimetric studies suggest that EDA molecules are successfully substituting the original metal-bound DMF. This modification not only enhances the material's carbon dioxide sorption capacity, increasing stability to repeated CO2 sorption cycles, but also improves the framework's stability to moisture. Moreover, this is one of the first amine-modified MOFs that can demonstrably be synthesized using recycled solvent, potentially reducing the future costs of production at larger scales.

| S-EPMC7137959 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data