Ontology highlight
ABSTRACT:
SUBMITTER: Cadranel A
PROVIDER: S-EPMC5674176 | biostudies-other | 2017 Nov
REPOSITORIES: biostudies-other
Cadranel Alejandro A Oviedo Paola S PS Pieslinger German E GE Yamazaki Shiori S Kleiman Valeria D VD Baraldo Luis M LM Guldi Dirk M DM
Chemical science 20170829 11
The picosecond excited state dynamics of [Ru(tpm)(bpy)(NCS)]<sup>+</sup> (<b>RubNCS<sup>+</sup></b> ) and [Ru(tpm)(bpy)(CN)]<sup>+</sup> (<b>RubCN<sup>+</sup></b> ) (tpm = tris(1-pyrazolyl)methane, bpy = 2,2'-bipyridine) have been analyzed by means of transient absorption measurements and spectroelectrochemistry. Emissive <sup>3</sup>MLCTs with (GS)HOMO(h<sup>+</sup>)-(GS)LUMO(e<sup>-</sup>) configurations are the lowest triplet excited states regardless of whether 387 or 505 nm photoexcitation ...[more]