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Crystal structure of 4-meth-oxy-N-(piperidine-1-carbono-thio-yl)benzamide.

ABSTRACT: In the title compound, C14H18N2O2S, the piperidine ring has a chair conformation. Its mean plane is twisted with respect to the 4-meth-oxy-benzoyl ring, with a dihedral angle of 63.0?(3)°. The central N-C(=S)-N(H)-C(=O) bridge is twisted with an N-C-N-C torsion angle of 74.8?(6)°. In the crystal, mol-ecules are linked by N-H?O and C-H?O hydrogen bonds, forming chains along the c-axis direction. Adjacent chains are linked by C-H?? inter-actions, forming layers parallel to the ac plane. The layers are linked by offset ?-? inter-actions [inter-centroid distance = 3.927?(3)?Å], forming a supra-molecular three-dimensional structure.

SUBMITTER: Suhud K

PROVIDER: S-EPMC5730311 | biostudies-other | 2017 Oct

REPOSITORIES: biostudies-other

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Crystal structure of 4-meth-oxy-N-(piperidine-1-carbono-thio-yl)benzamide.

Suhud Khairi K Hasbullah Siti Aishah SA Ahmad Musa M Heng Lee Yook LY Kassim Mohammad B MB

Acta crystallographica. Section E, Crystallographic communications 20170925 Pt 10

In the title compound, C14H18N2O2S, the piperidine ring has a chair conformation. Its mean plane is twisted with respect to the 4-meth-oxy-benzoyl ring, with a dihedral angle of 63.0 (3)°. The central N-C(=S)-N(H)-C(=O) bridge is twisted with an N-C-N-C torsion angle of 74.8 (6)°. In the crystal, mol-ecules are linked by N-H⋯O and C-H⋯O hydrogen bonds, forming chains along the c-axis direction. Adjacent chains are linked by C-H⋯π inter-actions, ...[more]

PMID: 29250374

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