Signatures of Plexitonic States in Molecular Electroluminescence.
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ABSTRACT:
SUBMITTER: Bergfield JP
PROVIDER: S-EPMC5797164 | biostudies-other | 2018 Feb
REPOSITORIES: biostudies-other
Publications
Signatures of Plexitonic States in Molecular Electroluminescence.
Bergfield Justin P JP Hendrickson Joshua R JR
Scientific reports 20180202 1
We develop a quantum master equation (QME) approach to investigate the electroluminesence (EL) of molecules confined between metallic electrodes and coupled to quantum plasmonic modes. Within our general state-based framework, we describe electronic tunneling, vibrational damping, environmental dephasing, and the quantum coherent dynamics of coupled quantum electromagnetic field modes. As an example, we calculate the STM-induced spontaneous emission of a tetraphenylporphyrin (TPP) molecule coupl ...[more]
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