Ontology highlight
ABSTRACT:
SUBMITTER: Franke SM
PROVIDER: S-EPMC5811169 | biostudies-other | 2015 Jan
REPOSITORIES: biostudies-other
Chemical science 20140929 1
We report the syntheses, electronic properties, and molecular structures of a series of mono- and dinuclear uranium(iv) hydrochalcogenido complexes supported by the sterically demanding but very flexible, single N-anchored tris(aryloxide) ligand (<sup>Ad</sup>ArO)<sub>3</sub>N)<sup>3-</sup>. The mononuclear complexes [((<sup>Ad</sup>ArO)<sub>3</sub>N)U(DME)(EH)] (E = S, Se, Te) can be obtained from the reaction of the uranium(iii) starting material [((<sup>Ad</sup>ArO)<sub>3</sub>N)U<sup>III</su ...[more]