Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Cobalt-Bridged Ionic Liquid Polymer on a Carbon Nanotube for Enhanced Oxygen Evolution Reaction Activity.

ABSTRACT: By taking inspiration from the catalytic properties of single-site catalysts and the enhancement of performance through ionic liquids on metal catalysts, we exploited a scalable way to place single cobalt ions on a carbon-nanotube surface bridged by polymerized ionic liquid. Single dispersed cobalt ions coordinated by ionic liquid are used as heterogeneous catalysts for the oxygen evolution reaction (OER). Performance data reveals high activity and stable operation without chemical instability.

SUBMITTER: Ding Y

PROVIDER: S-EPMC5887870 | biostudies-other | 2018 Mar

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Cobalt-Bridged Ionic Liquid Polymer on a Carbon Nanotube for Enhanced Oxygen Evolution Reaction Activity.

Ding Yuxiao Y Klyushin Alexander A Huang Xing X Jones Travis T Teschner Detre D Girgsdies Frank F Rodenas Tania T Schlögl Robert R Heumann Saskia S

Angewandte Chemie (International ed. in English) 20180221 13

By taking inspiration from the catalytic properties of single-site catalysts and the enhancement of performance through ionic liquids on metal catalysts, we exploited a scalable way to place single cobalt ions on a carbon-nanotube surface bridged by polymerized ionic liquid. Single dispersed cobalt ions coordinated by ionic liquid are used as heterogeneous catalysts for the oxygen evolution reaction (OER). Performance data reveals high activity and stable operation without chemical instability. ...[more]

PMID: 29316096

Similar Datasets

Cobalt-Based Coordination Polymer for Oxygen Reduction Reaction.

Project description:Lack of control over the structure and electrically nonconductive properties of coordination polymers (CPs) creates a major hindrance to designing an active electrocatalyst for oxygen reduction reaction (ORR). Here, we report a new semiconductive and low-optical band gap CP structure [{Co3(μ3-OH)(BTB)2(BPE)2}{Co0.5N(C5H5)}], 1, that exhibits high-performance ORR in alkaline medium. The electrical conductivity of compound 1 was measured using impedance spectroscopy and found to be 5 × 10-4 S cm-1. The Ketjenblack EC-600JD carbon used as a support for all the electrochemical methods such as cyclic voltammetry, rotating disk electrode, rotating ring-disk electrode and Koutecký-Levich analysis. The as-synthesized Co-based catalyst has the ability to reduce O2 to H2O by a nearly four-electron process. The crystal structure of 1 shows that the trimeric unit {Co3(μ3-OH)(COO)5N3} and monomeric unit {Co(COO)2(NC5H4)2}2+ are linked with BTB and BPE linkers to form a three-dimensional structure. Theoretical calculations predict that the monomeric center acts as an active catalytic site for ORR. This could be due to the efficient overlap of highest occupied molecular orbital-lowest unoccupied molecular orbital between monomer and O2 molecule. This CP, 1, shows facile 3.6-electron ORR, and it is inexpensive compared with widely used Pt catalysts. Therefore, this CP can be used as a promising cathode material for fuel cells in terms of efficiency and cost effectiveness.

| S-EPMC6641600 | biostudies-literature

Highly efficient and self-supported 3D carbon nanotube composite electrode for enhanced oxygen reduction reaction.

Project description:A binder-free and self-supported 3D carbon nanotube composite electrode with NiFe nanoalloys, N doping and Fe/Ni-N x -C structures was fabricated by a facile method. The strong synergistic effects of multi-components and the unique structural merits of the optimized sample endowed it outstanding oxygen reduction reaction activity with an onset potential of 1.048 V vs. RHE in 0.1 M KOH solution.

| S-EPMC9044186 | biostudies-literature

Composite Structural Supercapacitors: High-Performance Carbon Nanotube Supercapacitors through Ionic Liquid Localisation.

Project description:Composite structural supercapacitors (SSC) are an attractive technology for aerospace vehicles; however, maintaining strength whilst adding energy storage to composite structures has been difficult. Here, SSCs were manufactured using aerospace-grade composite materials and CNT mat electrodes. A new design methodology was explored where the supercapacitor electrolyte was localised within the composite structure, achieving good electrochemical performance within the active region, whilst maintaining excellent mechanical performance elsewhere. The morphologies of these localised SSC designs were characterised with synchrotron X-ray fluorescence microscopy and synchrotron X-ray micro-computed tomography and could be directly correlated with both electrochemical and mechanical performance. One configuration used an ionogel with an ionic liquid (IL) electrolyte, which assisted localisation and achieved 2640 mW h kg-1 at 8.37 W kg-1 with a corresponding short beam shear (SBS) strength of 71.5 MPa in the active area. A separate configuration with only IL electrolyte achieved 758 mW h kg-1 at 7.87 W kg-1 with SBS strength of 106 MPa in the active area. Both configurations provide a combined energy and strength superior to results previously reported in the literature for composite SSCs.

| S-EPMC9330893 | biostudies-literature

Ionic liquid flow along the carbon nanotube with DC electric field.

Project description:Liquid pumping can occur along the outer surface of an electrode under a DC electric field. For biological applications, a better understanding of the ionic solution pumping mechanism is required. Here, we fabricated CNT wire electrodes (CWEs) and tungsten wire electrodes (TWEs) of various diameters to assess an ionic solution pumping. A DC electric field created by a bias of several volts pumped the ionic solution in the direction of the negatively biased electrode. The resulting electro-osmotic flow was attributed to the movement of an electric double layer near the electrode, and the flow rates along the CWEs were on the order of picoliters per minute. According to electric field analysis, the z-directional electric field around the meniscus of the small electrode was more concentrated than that of the larger electrode. Thus, the pumping effect increased as the electrode diameter decreased. Interestingly in CWEs, the initiating voltage for liquid pumping did not change with increasing diameter, up to 20 ?m. We classified into three pumping zones, according to the initiating voltage and faradaic reaction. Liquid pumping using the CWEs could provide a new method for biological studies with adoptable flow rates and a larger 'Recommended pumping zone'.

| S-EPMC4488867 | biostudies-other

Grafting Cobalt Diselenide on Defective Graphene for Enhanced Oxygen Evolution Reaction.

Project description:Cobalt diselenide (CoSe2) has been demonstrated to be an efficient and economic electrocatalyst for oxygen evolution reaction (OER) both experimentally and theoretically. However, the catalytic performance of up-to-now reported CoSe2-based OER catalysts is still far below commercial expectation. Herein, we report a hybrid catalyst consisting of CoSe2 nanosheets grafted on defective graphene (DG). This catalyst exhibits a largely enhanced OER activity and robust stability in alkaline solution (overpotential at 10 mA cm-2: 270 mV; Tafel plots: 64 mV dec-1). Both experimental evidence and density functional theory calculations reveal that the outstanding OER performance of this hybrid catalyst can be attributed to the synergetic effect of exposed cobalt atoms and carbon defects (electron transfer from CoSe2 layer to defect sites at DG). Our results suggest a promising way for the development of highly efficient and low-cost OER catalysts based on transition metal dichalcogenides.

| S-EPMC6154397 | biostudies-literature

Coherent nanoscale cobalt/cobalt oxide heterostructures embedded in porous carbon for the oxygen reduction reaction.

Project description:Cost-effective and efficient electrocatalysts for the oxygen reduction reaction (ORR) are crucial for fuel cells and metal-air batteries. Herein, we report the facile synthesis of a Co/CoO/Co3O4 heterostructure embedded in a porous carbon matrix by refluxing and annealing. This composite exhibits several structural merits for catalyzing the ORR: (1) the existence of metallic Co and graphitic carbon enhanced the electrical conduction; (2) the porous, loose carbon network facilitated the electrolyte permeation and mass transport; (3) more importantly, the nanosized coherent CoO/Co3O4 heterojunctions with structural defects and oxygen vacancies enhanced the charge transport/separation at the interface and adsorption affinity to O2, thus promoting the ORR kinetics and lowering the reaction barrier. Consequently, the composite electrode manifests high electrocatalytic activity, attaining a current density of 6.7 mA cm-2 at -0.8 V (vs. Ag/AgCl), which is superior to pure CoO nanoparticles (4.7 mA cm-2), and has good methanol tolerance. The present strategy based on heterostructure and vacancy engineering may pave the way for the exploration of more advanced, low-cost electrocatalysts for electrochemical reduction and evolution processes.

| S-EPMC9084347 | biostudies-literature

Biochar-Based Graphitic Carbon Nitride Adorned with Ionic Liquid Containing Acidic Polymer: A Versatile, Non-Metallic Catalyst for Acid Catalyzed Reaction.

Project description:A novel biochar-based graphitic carbon nitride was prepared through calcination of Zinnia grandiflora petals and urea. To provide acidic and ionic-liquid functionalities on the prepared carbon, the resultant biochar-based graphitic carbon nitride was vinyl functionalized and polymerized with 2-acrylamido-2-methyl-1-propanesulfonic acid, acrylic acid and the as-prepared 1-vinyl-3-butylimidazolium chloride. The final catalytic system that benefits from both acidic (-COOH and -SO3H) and ionic-liquid functionalities was applied as a versatile, metal-free catalyst for promoting some model acid catalyzed reactions such as Knoevenagel condensation and Biginelli reaction in aqueous media under a very mild reaction condition. The results confirmed high activity of the catalyst. Broad substrate scope and recyclability and stability of the catalyst were other merits of the developed protocols. Comparative experiments also indicated that both acidic and ionic-liquid functionalities on the catalyst participated in the catalysis.

| S-EPMC7766038 | biostudies-literature

Chemically Enhanced Polymer-Coated Carbon Nanotube Electronic Gas Sensor for Isopropyl Alcohol Detection.

Project description:Breathing-air quality within commercial airline cabins has come under increased scrutiny because of the identification of volatile organic compounds (VOCs) from the engine bleed air used to provide oxygen to cabins. Ideally, a sensor would be placed within the bleed air pipe itself, enabling detection before it permeated through and contaminated the entire cabin. Current gas-phase sensors suffer from issues with selectivity, do not have the appropriate form factor, or are too complex for commercial deployment. Here, we chose isopropyl alcohol (IPA), a main component of de-icer spray used in the aerospace community, as a target analyte: IPA exposure has been hypothesized to be a key component of aerotoxic syndrome in pre, during, and postflight. IPAs proposed mechanism of action is that of an anesthetic and central nervous system depressant. In this work, we describe IPA sensor development by showing (1) the integration of a polymer as an IPA capture matrix, (2) the adoption of a redox chemical additives as an IPA oxidizer, and (3) the application of carbon nanotubes as an electronic sensing conduit. We demonstrate the ability to not only detect IPA at 100-10 000 ppm in unfiltered, laboratory air but also discriminate among IPA, isoprene, and acetone, especially in comparison to a typical photoionization detector. Overall, we show an electronic device that operates at room temperature and responds preferentially to IPA, where the increase in the resistance corresponds directly to the concentration of IPA. Ultimately, this study opens up the pathway to selective electronic sensors that can enable real-time monitoring in a variety of environments for the force health prevention and protection, and the potential through future work to enable low parts-per-million and possibly high parts-per-billion selective detection of gas-phase VOCs of interest.

| S-EPMC6644726 | biostudies-literature

High Electromechanical Response of Ionic Polymer Actuators with Controlled-Morphology Aligned Carbon Nanotube/Nafion Nanocomposite Electrodes.

Project description:Recent advances in fabricating controlled-morphology vertically aligned carbon nanotubes (VA-CNTs) with ultrahigh volume fraction create unique opportunities for markedly improving the electromechanical performance of ionic polymer conductor network composite (IPCNC) actuators. Continuous paths through inter-VA-CNT channels allow fast ion transport, and high electrical conduction of the aligned CNTs in the composite electrodes lead to fast device actuation speed (>10% strain/second). One critical issue in developing advanced actuator materials is how to suppress the strain that does not contribute to the actuation (unwanted strain) thereby reducing actuation efficiency. Here our experiments demonstrate that the VA-CNTs give an anisotropic elastic response in the composite electrodes, which suppresses the unwanted strain and markedly enhances the actuation strain (>8% strain under 4 volts). The results reported here suggest pathways for optimizing the electrode morphology in IPCNCs using ultra-high volume fraction VA-CNTs to further enhanced performance.

| S-EPMC3134233 | biostudies-literature

Formation of Single-Holed Cobalt/N-Doped Carbon Hollow Particles with Enhanced Electrocatalytic Activity toward Oxygen Reduction Reaction in Alkaline Media.

Project description:Design and construction of metal-organic framework (MOF) composite precursors have recently been considered as a promising strategy for the preparation of different structured metal/carbon-based functional materials. Here, an MOF composite-assisted strategy to synthesize single-holed cobalt/N-doped carbon hollow particles is reported. The yolk-shell polystyrene@zeolitic imidazolate framework-67 (PS@ZIF-67) composite precursors are first synthesized, followed by a controlled pyrolysis to obtain cobalt/N-doped carbon hollow particles with a large single hole on each shell. Moreover, the MOF-coating approach reported in this work can be extended to prepare various core-shell ZIF-67 composites with different structures and compositions. Benefiting from the structural and compositional advantages, the as-derived single-holed cobalt/N-doped carbon hollow particles manifest superior electrocatalytic oxygen reduction performance with high activity and excellent durability.

| S-EPMC5644236 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data