Ontology highlight
ABSTRACT:
SUBMITTER: Sun CY
PROVIDER: S-EPMC5897847 | biostudies-other | 2018 Feb
REPOSITORIES: biostudies-other
Sun Chun-Yi CY To Wai-Pong WP Hung Faan-Fung FF Wang Xin-Long XL Su Zhong-Min ZM Che Chi-Ming CM
Chemical science 20180201 8
Pincer platinum(ii) complexes are well documented to exhibit weak intermolecular interactions in the solid state and 77 K glassy solutions, leading to emissive triplet metal-metal-to-ligand charge transfer (<sup>3</sup>MMLCT) excited states that often vanish in dilute solutions. In this work, metal-organic framework (MOF) materials are introduced to provide a "solid solution" environment for easy access to <sup>3</sup>MMLCT excited states of pincer platinum(ii) complexes. Phosphorescent composit ...[more]