Unknown

Dataset Information

0

Synthesis of the RTH-type layer: the first small-pore, two dimensional layered zeolite precursor.


ABSTRACT: There are several distinct two-dimensional zeolite building layers that can condense through different stacking arrangements of the layers to form various three-dimensional framework materials. All known building layers are dense layers in that they do not contain 8-membered ring (MR) or larger pores perpendicular to the two-dimensional layers. Herein, we report a new material (CIT-10) that consists of a two-dimensional layer (termed "rth" layer) that contains an 8 MR perpendicular to the layer. Calcination of CIT-10 forms pure-silica RTH (SSZ-50). CIT-10 can be pillared to form a new framework material with a three-dimensional pore system of 8 and 10 MRs, denoted CIT-11, that can be calcined to form a new microporous material, denoted CIT-12.

SUBMITTER: Schmidt JE 

PROVIDER: S-EPMC5950832 | biostudies-other | 2015 Oct

REPOSITORIES: biostudies-other

altmetric image

Publications

Synthesis of the RTH-type layer: the first small-pore, two dimensional layered zeolite precursor.

Schmidt Joel E JE   Xie Dan D   Davis Mark E ME  

Chemical science 20150727 10


There are several distinct two-dimensional zeolite building layers that can condense through different stacking arrangements of the layers to form various three-dimensional framework materials. All known building layers are dense layers in that they do not contain 8-membered ring (MR) or larger pores perpendicular to the two-dimensional layers. Herein, we report a new material (CIT-10) that consists of a two-dimensional layer (termed "rth" layer) that contains an 8 MR perpendicular to the layer.  ...[more]

Similar Datasets

| S-EPMC8376903 | biostudies-literature
| S-EPMC6720306 | biostudies-literature
| S-EPMC6641246 | biostudies-literature
| S-EPMC7517411 | biostudies-literature
| S-EPMC8310756 | biostudies-literature
| S-EPMC7181601 | biostudies-literature
| S-EPMC9481117 | biostudies-literature
| S-EPMC5811170 | biostudies-literature
| S-EPMC10502664 | biostudies-literature
| S-EPMC6560128 | biostudies-literature