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A unified formulation of dichroic signals using the Borrmann effect and twisted photon beams.


ABSTRACT: Dichroic X-ray signals derived from the Borrmann effect and a twisted photon beam with topological charge l?=?1 are formulated with an effective wavevector. The unification applies for non-magnetic and magnetic materials. Electronic degrees of freedom associated with an ion are encapsulated in multipoles previously used to interpret conventional dichroism and Bragg diffraction enhanced by an atomic resonance. A dichroic signal exploiting the Borrmann effect with a linearly polarized beam presents charge-like multipoles that include a hexadecapole. A difference between dichroic signals obtained with a twisted beam carrying spin polarization (circular polarization) and opposite winding numbers presents charge-like atomic multipoles, whereas a twisted beam carrying linear polarization alone presents magnetic (time-odd) multipoles. Charge-like multipoles include a quadrupole, and magnetic multipoles include a dipole and an octupole. We discuss the practicalities and relative merits of spectroscopy exploiting the two remarkably closely-related processes. Signals using beams with topological charges l ? 2 present additional atomic multipoles.

SUBMITTER: Collins SP 

PROVIDER: S-EPMC5962556 | biostudies-other | 2018 May

REPOSITORIES: biostudies-other

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A unified formulation of dichroic signals using the Borrmann effect and twisted photon beams.

Collins Stephen P SP   Lovesey Stephen W SW  

Scientific reports 20180521 1


Dichroic X-ray signals derived from the Borrmann effect and a twisted photon beam with topological charge l = 1 are formulated with an effective wavevector. The unification applies for non-magnetic and magnetic materials. Electronic degrees of freedom associated with an ion are encapsulated in multipoles previously used to interpret conventional dichroism and Bragg diffraction enhanced by an atomic resonance. A dichroic signal exploiting the Borrmann effect with a linearly polarized beam present  ...[more]

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