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Crystal structure of 1-[3,5-bis-(tri-fluoro-meth-yl)phen-yl]-2-bromo-ethan-1-one.

ABSTRACT: The title compound, C10H5BrF6O, synthesized via continuous stirring of 3,5-bis-(tri-fluoro-meth-yl) aceto-phenone with bromine in an acidic medium and concentrated under reduced pressure, crystallizes with four mol-ecules in the unit cell (Z = 4) and one formula unit in the asymmetric unit. In the crystal, mol-ecules are linked in a head-to-tail fashion into dimers along the b-axis direction through weak C-H?Br and C-O?Csp2 inter-actions. C-H?O, C-F?? and F?F inter-actions are also observed.

SUBMITTER: Chandrashekharappa S

PROVIDER: S-EPMC6002836 | biostudies-other | 2018 Jun

REPOSITORIES: biostudies-other

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Crystal structure of 1-[3,5-bis-(tri-fluoro-meth-yl)phen-yl]-2-bromo-ethan-1-one.

Chandrashekharappa Sandeep S Bairagi Keshab M KM Mohan Mahendra K MK Mohanlall Viresh V Kasumbwe Kabange K Venugopala Katharigatta N KN Nayak Susanta K SK

Acta crystallographica. Section E, Crystallographic communications 20180531 Pt 6

The title compound, C10H5BrF6O, synthesized via continuous stirring of 3,5-bis-(tri-fluoro-meth-yl) aceto-phenone with bromine in an acidic medium and concentrated under reduced pressure, crystallizes with four mol-ecules in the unit cell (Z = 4) and one formula unit in the asymmetric unit. In the crystal, mol-ecules are linked in a head-to-tail fashion into dimers along the b-axis direction through weak C-H⋯Br and C-O⋯Csp2 ...[more]

PMID: 29951247

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