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Tandem Lewis Pair Polymerization and Organocatalytic Ring-Opening Polymerization for Synthesizing Block and Brush Copolymers.

ABSTRACT: Lewis pair polymerization is a powerful method for preparing soluble polymers bearing pendant active vinyl groups by directly polymerizing dissymmetric divinyl polar monomers. Herein, we present a strategy for synthesizing block and brush copolymers via tandem Lewis pair polymerization of methacrylates, "thiol-ene" click reaction and organocatalytic ring-opening polymerization of lactide.

SUBMITTER: Sun XY

PROVIDER: S-EPMC6017872 | biostudies-other | 2018 Feb

REPOSITORIES: biostudies-other

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Tandem Lewis Pair Polymerization and Organocatalytic Ring-Opening Polymerization for Synthesizing Block and Brush Copolymers.

Sun Xing-Yu XY Ren Wei-Min WM Liu Si-Jie SJ Jia Yin-Bao YB Wang Yi-Ming YM Lu Xiao-Bing XB

Molecules (Basel, Switzerland) 20180221 2

Lewis pair polymerization is a powerful method for preparing soluble polymers bearing pendant active vinyl groups by directly polymerizing dissymmetric divinyl polar monomers. Herein, we present a strategy for synthesizing block and brush copolymers via tandem Lewis pair polymerization of methacrylates, "thiol-ene" click reaction and organocatalytic ring-opening polymerization of lactide. ...[more]

PMID: 29466304

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