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Direct electrochemical generation of organic carbonates by dehydrogenative coupling.

ABSTRACT: Organic carbonates are an important source for polycarbonate synthesis. However, their synthesis generally requires phosgene, sophisticated catalysts, harsh reaction conditions, or other highly reactive chemicals. We present the first direct electrochemical generation of mesityl methyl carbonate by C-H activation. Although this reaction pathway is still challenging concerning scope and efficiency, it outlines a new strategy for carbonate generation.

SUBMITTER: Gieshoff T

PROVIDER: S-EPMC6037012 | biostudies-other | 2018

REPOSITORIES: biostudies-other

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Direct electrochemical generation of organic carbonates by dehydrogenative coupling.

Gieshoff Tile T Trieu Vinh V Heijl Jan J Waldvogel Siegfried R SR

Beilstein journal of organic chemistry 20180627

Organic carbonates are an important source for polycarbonate synthesis. However, their synthesis generally requires phosgene, sophisticated catalysts, harsh reaction conditions, or other highly reactive chemicals. We present the first direct electrochemical generation of mesityl methyl carbonate by C-H activation. Although this reaction pathway is still challenging concerning scope and efficiency, it outlines a new strategy for carbonate generation. ...[more]

PMID: 30013685

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