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Crystal structure and Hirshfeld surface analysis of N,N'-bis-(3-tert-butyl-2-hy-droxy-5-methyl-benzyl-idene)ethane-1,2-di-amine.

ABSTRACT: The title compound, C26H36N2O2, crystallizes in the phenol-imine form. In the mol-ecule, there are intra-molecular O-H?N hydrogen bonds forming S(6) ring motifs, and the two aromatic rings are inclined to each other by 37.9?(7)°. In the crystal, mol-ecules are linked by pairs of weak C-H?O hydrogen bonds, forming inversion dimers. Hirshfeld surface analysis and two-dimensional fingerprint plots indicate that the most important contributions to the crystal packing are from H?H (77.5%), H?C/C?H (16%), H?O/O?H (3.1%) and H?N/N?H (1.7%) inter-actions.

SUBMITTER: Sen P 

PROVIDER: S-EPMC6073007 | biostudies-other | 2018 Aug

REPOSITORIES: biostudies-other

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Crystal structure and Hirshfeld surface analysis of <i>N</i>,<i>N</i>'-bis-(3-<i>tert</i>-butyl-2-hy-droxy-5-methyl-benzyl-idene)ethane-1,2-di-amine.

Sen Pinar P   Kansiz Sevgi S   Golenya Irina A IA   Dege Necmi N  

Acta crystallographica. Section E, Crystallographic communications 20180724 Pt 8

The title compound, C<sub>26</sub>H<sub>36</sub>N<sub>2</sub>O<sub>2</sub>, crystallizes in the phenol-imine form. In the mol-ecule, there are intra-molecular O-H⋯N hydrogen bonds forming <i>S</i>(6) ring motifs, and the two aromatic rings are inclined to each other by 37.9 (7)°. In the crystal, mol-ecules are linked by pairs of weak C-H⋯O hydrogen bonds, forming inversion dimers. Hirshfeld surface analysis and two-dimensional fingerprint plots indicate that the most important contributions to t  ...[more]

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