Ultrasound-induced gelation of a giant macrocycle.
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ABSTRACT:
SUBMITTER: Nunez-Villanueva D
PROVIDER: S-EPMC6156880 | biostudies-other | 2018 Sep
REPOSITORIES: biostudies-other
Publications
Ultrasound-induced gelation of a giant macrocycle.
Núñez-Villanueva Diego D Jinks Michael A MA Gómez Magenti Jorge J Hunter Christopher A CA
Chemical communications (Cambridge, England) 20180901 77
A 68-membered macrocycle undergoes ultrasound-induced supramolecular gelation in acetonitrile. The sonogel shows a remarkable thermostability, indicating that self-assembly is mediated by exceptionally robust non-covalent interactions. Model compounds indicate that the macrocyclic topology is essential for gelation to occur. ...[more]
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