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Direct Enzymatic Glucose/O2 Biofuel Cell based on Poly-Thiophene Carboxylic Acid alongside Gold Nanostructures Substrates Derived through Bipolar Electrochemistry.

ABSTRACT: Bipolar electrochemistry (BPE) has been lately explored as a simple, reliable and novel electrochemical technique for the adjustment of various conductive substrates. Herein, BPE is performed to derive both of cathode and anode electrodes for the development of mediatorless/membraneless biofuel cell (BFC). On one hand, a preferable substrate for immobilization of bilirubin oxidase enzyme is prepared based on the electropolymerization of thiophene-3-carboxcylic acid (TCA) on an Au microfilm as a bipolar electrode. The resulted biocathode as novel bioelectrocatalyst offers a high electrocatalytic activity toward direct oxygen reduction reaction (ORR) with onset potential and current density of 0.55?V (vs. Ag/AgCl) and 867??A cm-2, respectively. On the other hand, another analogous Au bipolar electrode is electroplated through BPE to derive Au nanostructures (AuNSs). This modified Au electrode is utilized as an anodic platform for immobilization of flavin adenine dinucleotide-dependent glucose dehydrogenase (FAD-GDH) enzyme aimed at electrocatalytic glucose oxidation. The prepared bioanode displays a current density of 2.7?mA?cm-2 with onset potential of -0.03?V. Finally, the proposed bioanode and biocacthode in an assembled membraneless glucose/O2 BFC offers a power output of 146??W cm-2 with open circuit voltage of 0.54?V. This novel BPE method provides disposable electrochemical platforms for design of novel sensors, biosensors or other devices.

SUBMITTER: Gholami F

PROVIDER: S-EPMC6180125 | biostudies-other | 2018 Oct

REPOSITORIES: biostudies-other

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Direct Enzymatic Glucose/O<sub>2</sub> Biofuel Cell based on Poly-Thiophene Carboxylic Acid alongside Gold Nanostructures Substrates Derived through Bipolar Electrochemistry.

Gholami Fereshte F Navaee Aso A Salimi Abdollah A Ahmadi Rezgar R Korani Azam A Hallaj Rahman R

Scientific reports 20181010 1

Bipolar electrochemistry (BPE) has been lately explored as a simple, reliable and novel electrochemical technique for the adjustment of various conductive substrates. Herein, BPE is performed to derive both of cathode and anode electrodes for the development of mediatorless/membraneless biofuel cell (BFC). On one hand, a preferable substrate for immobilization of bilirubin oxidase enzyme is prepared based on the electropolymerization of thiophene-3-carboxcylic acid (TCA) on an Au microfilm as a ...[more]

PMID: 30305656

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Project description:Enabled by the proliferation of nanoscale fabrication techniques required to create spatially-repeating, sub-wavelength structures to manipulate the behavior of visible-wavelength radiation, optical metamaterials are of increasing interest. Here we develop and characterize a chemical sensing approach based on electrochemical tuning of the optical response function of large-area, inexpensive nanoaperture metamaterials at visible and near-IR wavelengths. Nanosphere lithography is used to create an ordered array of sub-wavelength apertures in a Au film. The spacing of these apertures is established during fabrication, based on the size of the polystyrene nanospheres. Tunable shifts in the transmission spectrum can be produced post-fabrication by electrodeposition of a dissimilar metal, Ag, using the nanoaperture film as one electrode in a 2-electrode closed bipolar electrochemical (CBE) cell, altering hole size, film thickness, and film composition while maintaining hole spacing dictated by the original pattern. Optical transmission spectra acquired under galvanostatic conditions can be expressed as a linear combination of the initial and final (saturated) spectra, and the resulting response function exhibits a sigmoidal response with respect to the amount of charge (or metal) deposited. This architecture is then used to perform optical coulometry of model analytes in a CBE-based analyte-reporter dual cell device, thus expanding the capability of CBE-based sensors. Increasing the exposed electrode area of the analyte cell increases the response of the device, while modifying the circuit resistance alters the balance between sensitivity and dynamic range. These tunable nanoaperture metamaterials exhibit enhanced sensitivity compared to CBE electrochromic reporter cells to the μM to nM concentration range, suggesting further avenues for development of CBE-based chemical sensors as well as application to inexpensive, point-of-care diagnostic devices.

Dataset Information

Direct Enzymatic Glucose/O2 Biofuel Cell based on Poly-Thiophene Carboxylic Acid alongside Gold Nanostructures Substrates Derived through Bipolar Electrochemistry.

Publications

Direct Enzymatic Glucose/O<sub>2</sub> Biofuel Cell based on Poly-Thiophene Carboxylic Acid alongside Gold Nanostructures Substrates Derived through Bipolar Electrochemistry.

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