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Outstanding Photoluminescence in Pr3+-Doped Perovskite Ceramics.

ABSTRACT: Ba (Zr0.2Ti0.8) O?-50% (Ba0.7Ca0.3) TiO? (BZT-0.5BCT) ceramics with different doping contents of Pr3+ were prepared by the conventional solid-state reaction. The phase structure and crystallinity of the fabricated ceramics were investigated by X-ray diffraction, Raman spectroscopy, and scanning electron microscopy. Photoluminescence (PL) emission spectra were measured to analyze the PL characteristics. The strong intensities of a green band at 489 nm and a red band at 610 nm were observed. The maximum emission intensity of the PL spectrum was achieved in the BZT-0.5BCT ceramic with 0.2% mol of Pr3+ ions. Furthermore, the PL spectra of BZT-0.5BCT ceramics were found to be sensitive to polarization of the ferroelectric ceramics. Compared with the unpoled ceramics, the green emission increased about 42% and a new emission peak at 430 nm appeared for the poled ceramics. With excellent intrinsic ferroelectricity and an enhanced PL property, such material has potential to realize multifunctionality in a wide application range.

SUBMITTER: Zhang J

PROVIDER: S-EPMC6187377 | biostudies-other | 2018 Aug

REPOSITORIES: biostudies-other

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Outstanding Photoluminescence in Pr3+-Doped Perovskite Ceramics.

Zhang Jiameng J Hao Yanan Y Bi Meihua M Dong Guoyan G Liu Xiaoming X Bi Ke K

Micromachines 20180821 9

Ba (Zr0.2Ti0.8) O₃-50% (Ba0.7Ca0.3) TiO₃ (BZT-0.5BCT) ceramics with different doping contents of Pr3+ were prepared by the conventional solid-state reaction. The phase structure and crystallinity of the fabricated ceramics were investigated by X-ray diffraction, Raman spectroscopy, and scanning electron microscopy. Photoluminescence (PL) emission spectra were measured to analyze the PL characteristics. The strong intensities of a green band ...[more]

PMID: 30424352

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Project description:This research study addresses the computational simulations of optical and nonlinear optical (NLO) characteristics of silver (Ag) cluster doped graphyne (GY) complexes. By precisely following DFT and TD-DFT hypothetical computations, in-depth characterization of GY@Agcenter, GY@Agside, GY@2Agperpendicular, GY@2Agabove, and GY@3Agcenter is accomplished using CAM-B3LYP/LANL2DZ while the CAM-B3LYP/mixed basis set is used for study of 2GY@Agcenter, 2GY@Agside, 2GY@2Agperpendicular, 2GY@2Agabove, and 2GY@3Agcenter. The effects of various graphyne surface based complexes on hyperpolarizabilities, frontier molecular orbitals (FMOs), density of states (DOS), absorption maximum (λ max), binding energy (E b), dipole moment (μ), electron density distribution map (EDDM), transition density matrix (TDM), electrostatic potential (ESP), vertical ionization energy (E VI) and electrical conductivity (σ) have been investigated. Infrared (IR), non-covalent interaction (NCI) analysis accompanied by isosurface are performed to study the vibrational frequencies and type of interaction. Doping strategies in all complexes impressively reformed charge transfer characteristics such as narrowing band gap (E g) in the range of 2.58-4.73 eV and enhanced λ max lying in the range of 368-536 nm as compared to pure GY with 5.78 eV E g and 265 nm λ max for (GY@Agcenter-GY@3Agcenter). In the case of (2GY@Agcenter-2GY@3Agcenter), when compared to 2GY with 5.58 eV E g and 275 nm absorption, maximum doping techniques have more effectively modified λ max in the region of 400-548 nm and E g, which is in the order of 2.55-4.62 eV. GY@3Agcenter and 2GY@3Agcenter reflected a noteworthy increment in linear polarizability α O (436.90 au) and (586 au) and the first hyperpolarizability β O (5048.77 au) and (17 270 au) because of their lowest excitation energy (ΔE) when studied in comparison with GY (α O = 281.54 and β O = 0.21 au) and 2GY surface (α O = 416 and β O = 0.06 au). Focusing on harmony between the tiny Ag clusters and graphyne surface as well as their influences on NLO properties, graphyne doping using its two-unit cells (2GY) is found to be expedient for the development of future nanoscale devices.

Dataset Information

Outstanding Photoluminescence in Pr3+-Doped Perovskite Ceramics.

Publications

Outstanding Photoluminescence in Pr<sup>3+</sup>-Doped Perovskite Ceramics.

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