Ontology highlight
ABSTRACT:
SUBMITTER: Sahoo B
PROVIDER: S-EPMC6238895 | biostudies-other | 2018 Nov
REPOSITORIES: biostudies-other
Chemical science 20180906 42
By applying N-doped carbon modified iron-based catalysts, the controlled hydrogenation of N-heteroarenes, especially (iso)quinolones, is achieved. Crucial for activity is the catalyst preparation by pyrolysis of a carbon-impregnated composite, obtained from iron(ii) acetate and <i>N</i>-aryliminopyridines. As demonstrated by TEM, XRD, XPS and Raman spectroscopy, the synthesized material is composed of Fe(0), Fe<sub>3</sub>C and FeN <sub><i>x</i></sub> in a N-doped carbon matrix. The decent catal ...[more]