Ontology highlight
ABSTRACT:
SUBMITTER: Kaya Y
PROVIDER: S-EPMC6274148 | biostudies-other | 2016 Jan
REPOSITORIES: biostudies-other
Kaya Yunus Y Yilmaz Veysel T VT Buyukgungor Orhan O
Molecules (Basel, Switzerland) 20160121 1
In this work, we report synthesis, crystallographic, spectroscopic and quantum chemical studies of a new imine oxime, namely (4-nitro-phenyl)-(1-phenyl-ethylimino)-acetaldehyde oxime (nppeieoH). Spectroscopic and X-ray diffraction studies showed that nppeieoH is hydrolyzed in aqueous solution, forming nitroisonitrosoacetophenone (ninap) and the hydrolysis product binds to Pd(II) to yield [Pd(nppeieo)(ninap)]. The mechanism of the hydrolysis reaction has been theoretically investigated in detail, ...[more]