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A Catalytic Cross-Olefination of Diazo Compounds with Sulfoxonium Ylides.

ABSTRACT: A ruthenium-catalysed cross-olefination of diazo compounds and sulfoxonium ylides is presented. Our reaction design exploits the intrinsic difference in reactivity of diazo compounds and sulfoxonium ylides as both carbene precursors and nucleophiles, which results in a highly selective reaction.

SUBMITTER: Neuhaus JD 

PROVIDER: S-EPMC6283242 | biostudies-other | 2018 Dec

REPOSITORIES: biostudies-other

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A Catalytic Cross-Olefination of Diazo Compounds with Sulfoxonium Ylides.

Neuhaus James D JD   Bauer Adriano A   Pinto Alexandre A   Maulide Nuno N  

Angewandte Chemie (International ed. in English) 20181108 49

A ruthenium-catalysed cross-olefination of diazo compounds and sulfoxonium ylides is presented. Our reaction design exploits the intrinsic difference in reactivity of diazo compounds and sulfoxonium ylides as both carbene precursors and nucleophiles, which results in a highly selective reaction. ...[more]

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