Unknown

Dataset Information

0

Crystal structure of poly[[hexa-aqua-tris-(?-3,6-di-oxo-cyclo-hexa-1,4-diene-1,4-diolato)dierbium(III)] octa-deca-hydrate].


ABSTRACT: The title lanthanide complex, [Er2(C6H2O4)3(H2O)6]·18H2O, is isostructural with its La, Gd, Yb and Lu analogues. The Er3+ ion, located on a threefold rotation axis, is nine-coordinated in a distorted tricapped trigonal-prismatic geometry, which is completed by six oxygen atoms from three dhbq2- ligands and three oxygen atoms from coordinated water mol-ecules. Each dhbq2- ligand acts in a ?2-bis-(bidentate) bridging mode to connect two Er3+ ions to form honeycomb (6,3) two-dimensional sheets extending in the ab plane, having an Er?Er separation of 8.7261?(2)?Å. In the crystal, extensive O-H?O hydrogen-bonding inter-actions involving the coordinated water mol-ecules and the water mol-ecules of crystallization, as well as the oxygen atoms of the dhbq2- ligands, generate an overall three-dimensional supra-molecular network.

SUBMITTER: Ponjan N 

PROVIDER: S-EPMC6323882 | biostudies-other | 2019 Jan

REPOSITORIES: biostudies-other

altmetric image

Publications

Crystal structure of poly[[hexa-aqua-tris-(μ-3,6-di-oxo-cyclo-hexa-1,4-diene-1,4-diolato)dierbium(III)] octa-deca-hydrate].

Ponjan Nutcha N   Kodchasanthong Kenika K   Jiajaroen Suwadee S   Chainok Kittipong K  

Acta crystallographica. Section E, Crystallographic communications 20190101 Pt 1


The title lanthanide complex, [Er<sub>2</sub>(C<sub>6</sub>H<sub>2</sub>O<sub>4</sub>)<sub>3</sub>(H<sub>2</sub>O)<sub>6</sub>]·18H<sub>2</sub>O, is isostructural with its La, Gd, Yb and Lu analogues. The Er<sup>3+</sup> ion, located on a threefold rotation axis, is nine-coordinated in a distorted tricapped trigonal-prismatic geometry, which is completed by six oxygen atoms from three dhbq<sup>2-</sup> ligands and three oxygen atoms from coordinated water mol-ecules. Each dhbq<sup>2-</sup> ligan  ...[more]

Similar Datasets

| S-EPMC2983139 | biostudies-literature
| S-EPMC3435695 | biostudies-literature
| S-EPMC3998435 | biostudies-literature
| S-EPMC3344551 | biostudies-literature
| S-EPMC3238691 | biostudies-literature
| S-EPMC4051031 | biostudies-literature
| S-EPMC3998558 | biostudies-literature
| S-EPMC2979923 | biostudies-literature
| S-EPMC3238874 | biostudies-literature
| S-EPMC3246972 | biostudies-literature