Browse
Submit Data
Databases
API
Help

Dataset Information

22 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Glucose/Graphene-Based Aerogels for Gas Adsorption and Electric Double Layer Capacitors.

ABSTRACT: In this study, three-dimensional glucose/graphene-based aerogels (G/GAs) were synthesized using the hydrothermal reduction and CO₂ activation method. Graphene oxide (GO) was used as a matrix, and glucose was used as a binder for the orientation of the GO morphology in an aqueous media. We determined that G/GAs exhibited narrow mesopore size distribution, a high surface area (763 m² g-1), and hierarchical macroporous and mesoporous structures. These features contributed to G/GAs being promising adsorbents for the removal of CO₂ (76.5 mg g-1 at 298 K), CH₄ (16.8 mg g-1 at 298 K), and H₂ (12.1 mg g-1 at 77 K). G/GAs presented excellent electrochemical performance, featuring a high specific capacitance of 305.5 F g-1 at 1 A g-1, and good cyclic stability of 98.5% retention after 10,000 consecutive charge-discharge cycles at 10 A g-1. This study provided an efficient approach for preparing graphene aerogels exhibiting hierarchical porosity for gas adsorption and supercapacitors.

SUBMITTER: Liu KK

PROVIDER: S-EPMC6401828 | biostudies-other | 2018 Dec

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Glucose/Graphene-Based Aerogels for Gas Adsorption and Electric Double Layer Capacitors.

Liu Kang-Kai KK Jin Biao B Meng Long-Yue LY

Polymers 20181228 1

In this study, three-dimensional glucose/graphene-based aerogels (G/GAs) were synthesized using the hydrothermal reduction and CO₂ activation method. Graphene oxide (GO) was used as a matrix, and glucose was used as a binder for the orientation of the GO morphology in an aqueous media. We determined that G/GAs exhibited narrow mesopore size distribution, a high surface area (763 m² g<sup>-1</sup>), and hierarchical macroporous and mesoporous structures. These features contributed to G/GAs being ...[more]

PMID: 30960024

Similar Datasets

How to Measure and Calculate Equivalent Series Resistance of Electric Double-Layer Capacitors.

Project description:Electric double-layer capacitors (EDLCs) are energy storage devices that have attracted attention from the scientific community due to their high specific power storage capabilities. The standard method for determining the maximum power (Pmax) of these devices uses the relation Pmax = U2/4RESR, where U stands for the cell voltage and RESR for the equivalent series resistance. Despite the relevance of RESR, one can observe a lack of consensus in the literature regarding the determination of this parameter from the galvanostatic charge-discharge findings. In addition, a literature survey revealed that roughly half of the scientific papers have calculated the RESR values using the electrochemical impedance spectroscopy (EIS) technique, while the other half used the galvanostatic charge discharge (GCD) method. RESR values extracted from EIS at high frequencies (>10 kHz) do not depend on the particular equivalent circuit model. However, the conventional GCD method better resembles the real situation of the device operation, and thus its use is of paramount importance for practical purposes. In the latter case, the voltage drop (?U) verified at the charge-discharge transition for a given applied current (I) is used in conjunction with Ohm's law to obtain the RESR (e.g., RESR = ?U/?I). However, several papers have caused a great confusion in the literature considering only applied current (I). In order to shed light on this important subject, we report in this work a rational analysis regarding the GCD method in order to prove that to obtain reliable RESR values the voltage drop must be normalized by a factor of two (e.g., RESR = ?U/2I).

| S-EPMC6515551 | biostudies-literature

Boron-doped Nanodiamond as an Electrode Material for Aqueous Electric Double-layer Capacitors.

Project description:Herein, a conductive boron-doped nanodiamond (BDND) particle is prepared as an electrode material for an aqueous electric double-layer capacitor with high power and energy densities. The BDND is obtained by depositing a boron-doped diamond (BDD) on a nanodiamond particle substrate with a primary particle size of 4.7 nm via microwave plasma-assisted chemical vapor deposition, followed by heat treatment in air. The BDND comprises BDD and sp2 carbon components, and exhibits a conductivity above 10-2 S cm-1 and a specific surface area of 650 m2 g-1. Cyclic voltammetry measurements recorded in 1 M H2SO4 at a BDND electrode in a two-electrode system shows a capacitance of 15.1 F g-1 and a wide potential window (cell voltage) of 1.8 V, which is much larger than that obtained at an activated carbon electrode, i.e., 0.8 V. Furthermore, the cell voltage of the BDND electrode reaches 2.8 V when using saturated NaClO4 as electrolyte. The energy and power densities per unit weight of the BDND for charging-discharging in 1 M H2SO4 at the BDND electrode cell are 10 Wh kg-1 and 104 W kg-1, respectively, and the energy and power densities per unit volume of the BDND layer are 3-4 mWh cm-3 and 10 W cm-3, respectively. Therefore, the BDND is a promising candidate for the development of a compact aqueous EDLC device with high energy and power densities.

| S-EPMC6882838 | biostudies-literature

Mesophase Pitch-Derived Carbons with High Electronic and Ionic Conductivity Levels for Electric Double-Layer Capacitors.

Project description:We develop a temperature-programmed pretreatment strategy for converting aliphatic-rich petroleum pitch into a mesophase framework, which can then be activated using KOH to produce high-performance carbons for electric double-layer capacitors (EDLCs). In the pretreatment of pitch at an optimal temperature, both the temperature ramp and holding time influence the mesophase structure, which governs the pore structure and crystallinity of the resulting activated carbon. High carbon microporosity is beneficial to capacitance maximization but detrimental to ion transport. To resolve this problem, we develop a multistep ramp incorporating aliphatic species into the aromatic framework during mesophase formation. This incorporation process produces a mesophase framework that can be activated to form carbons with high crystallinity, thereby enhancing electronic conductivity and hierarchical porosity, which improves ionic conductivity. The resulting carbon electrode is used to assemble a symmetric EDLC, which exhibits a capacitance of 160 F g-1 and excellent high-rate retention in a propylene carbonate solution of N,N-diethyl-N-methylethanaminium tetrafluoroborate. The EDLC delivers a superior specific energy of 40 Wh kg-1 (based on the total carbon mass) within a voltage range of 0-2.7 V and sustained a high energy of 24 Wh kg-1 at a high power of 50 kW kg-1. The findings of this study demonstrate that incorporating aliphatic species into aromatic mesophase frameworks plays a crucial role in regulating the crystallinity and pore structure of pitch-derived carbons for charge storage.

| S-EPMC6796889 | biostudies-literature

Reevaluation of Performance of Electric Double-layer Capacitors from Constant-current Charge/Discharge and Cyclic Voltammetry.

Project description:The electric characteristics of electric-double layer capacitors (EDLCs) are determined by their capacitance which is usually measured in the time domain from constant-current charging/discharging and cyclic voltammetry tests, and from the frequency domain using nonlinear least-squares fitting of spectral impedance. The time-voltage and current-voltage profiles from the first two techniques are commonly treated by assuming ideal RsC behavior in spite of the nonlinear response of the device, which in turn provides inaccurate values for its characteristic metrics [corrected]. In this paper we revisit the calculation of capacitance, power and energy of EDLCs from the time domain constant-current step response and linear voltage waveform, under the assumption that the device behaves as an equivalent fractional-order circuit consisting of a resistance Rs in series with a constant phase element (CPE(Q, α), with Q being a pseudocapacitance and α a dispersion coefficient). In particular, we show with the derived (Rs, Q, α)-based expressions, that the corresponding nonlinear effects in voltage-time and current-voltage can be encompassed through nonlinear terms function of the coefficient α, which is not possible with the classical RsC model. We validate our formulae with the experimental measurements of different EDLCs.

| S-EPMC5146949 | biostudies-literature

Hierarchical porous carbon foam electrodes fabricated from waste polyurethane elastomer template for electric double-layer capacitors.

Project description:Plastic waste has become a major global environmental concern. The utilization of solid waste-derived porous carbon for energy storage has received widespread attention in recent times. Herein, we report the comparison of electrochemical performance of porous carbon foams (CFs) produced from waste polyurethane (PU) elastomer templates via two different activation pathways. Electric double-layer capacitors (EDLCs) fabricated from the carbon foam exhibited a gravimetric capacitance of 74.4 F/g at 0.1 A/g. High packing density due to the presence of carbon spheres in the hierarchical structure offered excellent volumetric capacitance of 134.7 F/cm3 at 0.1 A/g. Besides, the CF-based EDLCs exhibited Coulombic efficiency close to 100% and showed stable cyclic performance for 5000 charge-discharge cycles with good capacitance retention of 97.7% at 3 A/g. Low equivalent series resistance (1.05 Ω) and charge transfer resistance (0.23 Ω) due to the extensive presence of hydroxyl functional groups contributed to attaining high power (48.89 kW/kg). Based on the preferred properties such as high specific surface area, hierarchical pore structure, surface functionalities, low metallic impurities, high conductivity and desirable capacitive behaviour, the CF prepared from waste PU elastomers have shown potential to be adopted as electrodes in EDLCs.

| S-EPMC9276828 | biostudies-literature

Electric double-layer capacitance between an ionic liquid and few-layer graphene.

Project description:Ionic-liquid gates have a high carrier density due to their atomically thin electric double layer (EDL) and extremely large geometrical capacitance Cg. However, a high carrier density in graphene has not been achieved even with ionic-liquid gates because the EDL capacitance CEDL between the ionic liquid and graphene involves the series connection of Cg and the quantum capacitance Cq, which is proportional to the density of states. We investigated the variables that determine CEDL at the molecular level by varying the number of graphene layers n and thereby optimising Cq. The CEDL value is governed by Cq at n < 4, and by Cg at n > 4. This transition with n indicates a composite nature for CEDL. Our finding clarifies a universal principle that determines capacitance on a microscopic scale, and provides nanotechnological perspectives on charge accumulation and energy storage using an ultimately thin capacitor.

| S-EPMC3615339 | biostudies-other

A Holey Graphene Additive for Boosting Performance of Electric Double-Layer Supercapacitors.

Project description:We demonstrate a facile and effective method, which is low-cost and easy to scale up, to fabricate holey graphene nanosheets (HGNSs) via ultrafast heating during synthesis. Various heating temperatures are used to modify the material properties of HGNSs. First, we use HGNSs as the electrode active materials for electric double-layer capacitors (EDLCs). A synthesis temperature of 900 °C seems to be optimal, i.e., the conductivity and adhesion of HGNSs reach a compromise. The gravimetric capacitance of this HGNS sample (namely HGNS-900) is 56 F·g-1. However, the volumetric capacitance is low, which hinders its practical application. Secondly, we incorporate activated carbon (AC) into HGNS-900 to make a composite EDLC material. The effect of the AC:HGNS-900 ratio on the capacitance, high-rate performance, and cycling stability are systematically investigated. With a proper amount of HGNS-900, both the electrode gravimetric and volumetric capacitances at high rate charging/discharging are clearly higher than those of plain AC electrodes. The AC/HGNS-900 composite is a promising electrode material for nonaqueous EDLC applications.

| S-EPMC7240531 | biostudies-literature

An Approach to Solid-State Electrical Double Layer Capacitors Fabricated with Graphene Oxide-Doped, Ionic Liquid-Based Solid Copolymer Electrolytes.

Project description:Solid polymer electrolyte (SPE) composed of semi-crystalline poly (vinylidene fluoride-hexafluoropropylene) [P(VdF-HFP)] copolymer, 1-ethyl-3-methylimidazolium bis (trifluoromethyl sulphonyl) imide [EMI-BTI] and graphene oxide (GO) was prepared and its performance evaluated. The effects of GO nano-filler were investigated in terms of enhancement in ionic conductivity along with the electrochemical properties of its electrical double layer capacitors (EDLC). The GO-doped SPE shows improvement in ionic conductivity compared to the P(VdF-HFP)-[EMI-BTI] SPE system due to the existence of the abundant oxygen-containing functional group in GO that assists in the improvement of the ion mobility in the polymer matrix. The complexation of the materials in the SPE is confirmed in X-ray diffraction (XRD) and thermogravimetric analysis (TGA) studies. The electrochemical performance of EDLC fabricated with GO-doped SPE is examined using cyclic voltammetry and charge-discharge techniques. The maximum specific capacitance obtained is 29.6 F∙g-1, which is observed at a scan rate of 3 mV/s in 6 wt % GO-doped, SPE-based EDLC. It also has excellent cyclic retention as it is able keep the performance of the EDLC at 94% even after 3000 cycles. These results suggest GO doped SPE plays a significant role in energy storage application.

| S-EPMC5456773 | biostudies-other

Correction: Correction: Electrode Mass Balancing as an Inexpensive and Simple Method to Increase the Capacitance of Electric Double-Layer Capacitors.

Project description:[This corrects the article DOI: 10.1371/journal.pone.0170135.].

| S-EPMC5352021 | biostudies-literature

Investigation of the Ionic Liquid Graphene Electric Double Layer in Supercapacitors Using Constant Potential Simulations.

Project description:In this work, we investigate the effect of the cation structure on the structure and dynamics of the electrode-electrolyte interface using molecular dynamics simulations. A constant potential method is used to capture the behaviour of 1-ethyl-3-methylimidazolium bis (trifluoromethane)sulfonimide ([C2mim][NTf2]) and butyltrimethylammonium bis(trifluoromethane) sulfonimide ([N4,1,1,1][NTf2]) ionic liquids at varying potential differences applied across the supercapacitor. We find that the details of the structure in the electric double layer and the dynamics differ significantly, yet the charge profile and capacitance do not vary greatly. For the systems considered, charging results in the rearrangement and reorientation of ions within ?1 nm of the electrode rather than the diffusion of ions to/from the bulk region. This occurs on timescales of O(10 ns) for the ionic liquids considered, and depends on the viscosity of the fluid.

| S-EPMC7693729 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data