Ontology highlight
ABSTRACT:
SUBMITTER: Klose J
PROVIDER: S-EPMC6466696 | biostudies-other | 2019
REPOSITORIES: biostudies-other
Beilstein journal of organic chemistry 20190403
The synthesis of mixed-ligand complexes of the type [M<sub>2</sub>L(μ-L')]<sup>+</sup>, where L represents a 24-membered macrocyclic hexaaza-dithiophenolate ligand, L' is an azobenzene carboxylate co-ligand, and M = Cd(II), Ni(II) or Zn(II), is reported. A series of new complexes were synthesized, namely [M<sub>2</sub>L(μ-L')]<sup>+</sup> (L' = azo-H, M = Cd (<b>1</b>), Ni (<b>2</b>); L' = azo-OH, M = Zn (<b>3</b>), Ni (<b>4</b>); L' = azo-NMe<sub>2</sub>, M = Zn (<b>5</b>), Cd (<b>6</b>), Ni (< ...[more]