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Targetable Mechanical Properties by Switching between Self-Sorting and Co-assembly with In Situ Formed Tripodal Ketoenamine Supramolecular Hydrogels.

ABSTRACT: A new family of supramolecular hydrogelators are introduced in which self-sorting and co-assembly can be utilised in the tuneability of the mechanical properties of the materials, a property closely tied to the nanostructure of the gel network. The in situ reactivity of the components of the gelators allows for system chemistry concepts to be applied to the formation of the gels and shows that molecular properties, and not necessarily the chemical identity, determines some gel properties in these family of gels.

SUBMITTER: Foster JS

PROVIDER: S-EPMC6473556 | biostudies-other | 2018 Aug

REPOSITORIES: biostudies-other

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Targetable Mechanical Properties by Switching between Self-Sorting and Co-assembly with <i>In Situ</i> Formed Tripodal Ketoenamine Supramolecular Hydrogels.

Foster Jamie S JS Prentice Andrew W AW Forgan Ross S RS Paterson Martin J MJ Lloyd Gareth O GO

ChemNanoMat : chemistry of nanomaterials for energy, biology and more 20180622 8

A new family of supramolecular hydrogelators are introduced in which self-sorting and co-assembly can be utilised in the tuneability of the mechanical properties of the materials, a property closely tied to the nanostructure of the gel network. The <i>in situ</i> reactivity of the components of the gelators allows for system chemistry concepts to be applied to the formation of the gels and shows that molecular properties, and not necessarily the chemical identity, determines some gel properties ...[more]

PMID: 31032176

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