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Molybdenum Disulfide Quantum Dots Prepared by Bipolar-Electrode Electrochemical Scissoring.


ABSTRACT: A convenient bipolar-electrode (BPE) electrochemical method was engineered to produce molybdenum disulfide (MoS2) quantum dots (QDs) using pure phosphate buffer (PBS) as the electrolyte and the MoS2 powder as the precursor. Meanwhile, the corresponding by-product precipitate was studied, in which MoS2 nanosheets were observed. The BPE design would not be restricted by the shape and size of the MoS2 precursor. It could lead to the defect generation and 2H → 1T phase variation of the MoS2, resulting in the formation of nanosheets and finally the QDs. The as-prepared MoS2 QDs exhibited high photoluminescence (PL) quantum yield of 13.9% and average lateral size of 4.4 ± 0.2 nm, respectively. Their excellent PL property, low cytotoxicity, and good aqueous dispersion offer promising applicability in PL staining and cell imaging. Meanwhile, the as-obtained byproduct containing the nanosheets could be used as an effective electromagnetic wave (EMW) absorber. The minimum reflection loss (RL) value was -54.13 dB at the thickness of 3.3 mm. The corresponding bandwidth with efficient attenuation (<-10 dB) was up to 7.04 GHz (8.8-15.84 GHz). The as-obtained EMW performance was far superior over most previously reported MoS2-based nanomaterials.

SUBMITTER: Li Y 

PROVIDER: S-EPMC6630415 | biostudies-other | 2019 Jun

REPOSITORIES: biostudies-other

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Molybdenum Disulfide Quantum Dots Prepared by Bipolar-Electrode Electrochemical Scissoring.

Li Yang Y   Wang Xiaoxia X   Liu Mengli M   Luo Heng H   Deng Lianwen L   Huang Lei L   Wei Shuang S   Zhou Congli C   Xu Yuanhong Y  

Nanomaterials (Basel, Switzerland) 20190621 6


A convenient bipolar-electrode (BPE) electrochemical method was engineered to produce molybdenum disulfide (MoS<sub>2</sub>) quantum dots (QDs) using pure phosphate buffer (PBS) as the electrolyte and the MoS<sub>2</sub> powder as the precursor. Meanwhile, the corresponding by-product precipitate was studied, in which MoS<sub>2</sub> nanosheets were observed. The BPE design would not be restricted by the shape and size of the MoS<sub>2</sub> precursor. It could lead to the defect generation and  ...[more]

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