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Mild synthesis of diboryldiborenes by diboration of B-B triple bonds.


ABSTRACT: A set of diboryldiborenes are prepared by the mild, catalyst-free, room-temperature diboration of the B-B triple bonds of doubly base-stabilized diborynes. Two of the product diboryldiborenes are found to be air- and water-stable in the solid state, an effect that is attributed to their high crystallinity and extreme insolubility in a wide range of solvents.

SUBMITTER: Bruckner T 

PROVIDER: S-EPMC6713863 | biostudies-other | 2019 Aug

REPOSITORIES: biostudies-other

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Mild synthesis of diboryldiborenes by diboration of B-B triple bonds.

Brückner Tobias T   Dewhurst Rian D RD   Dellermann Theresa T   Müller Marcel M   Braunschweig Holger H  

Chemical science 20190611 31


A set of diboryldiborenes are prepared by the mild, catalyst-free, room-temperature diboration of the B-B triple bonds of doubly base-stabilized diborynes. Two of the product diboryldiborenes are found to be air- and water-stable in the solid state, an effect that is attributed to their high crystallinity and extreme insolubility in a wide range of solvents. ...[more]

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