CO₂ Capture Membrane for Long-Cycle Lithium-Air Battery.

ABSTRACT: Lithium-air batteries (LABs) have attracted extensive attention due to their ultra-high energy density. At present, most LABs are operated in pure oxygen (O₂) since carbon dioxide (CO₂) under ambient air will participate in the battery reaction and generate an irreversible by-product of lithium carbonate (Li₂CO₃), which will seriously affect the performance of the battery. Here, to solve this problem, we propose to prepare a CO₂ capture membrane (CCM) by loading activated carbon encapsulated with lithium hydroxide (LiOH@AC) onto activated carbon fiber felt (ACFF). The effect of the LiOH@AC loading amount on ACFF has been carefully investigated, and CCM has an ultra-high CO₂ adsorption performance (137 cm³ g^-1) and excellent O₂ transmission performance by loading 80 wt% LiOH@AC onto ACFF. The optimized CCM is further applied as a paster on the outside of the LAB. As a result, the specific capacity performance of LAB displays a sharp increase from 27,948 to 36,252 mAh g^-1, and the cycle time is extended from 220 h to 310 h operating in a 4% CO₂ concentration environment. The concept of carbon capture paster opens a simple and direct way for LABs operating in the atmosphere.

SUBMITTER: Wang J 

PROVIDER: S-EPMC10003791 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature