Dataset Information

Recyclable Magnesium-Modified Biochar Beads for Efficient Removal of Phosphate from Wastewater.

ABSTRACT: Although ball milling is effective for biochar modification with metal oxides for efficient phosphate removal, the recyclability of the adsorbent as well as the precursors for modification, still need to be optimized. Herein, a magnesium-modified biochar was first prepared with the precursor of MgCl₂·6H₂O through the solvent-free ball milling method. After that, recyclable biochar beads were fabricated with the introduction of sodium alginate and Fe₃O_4. The beads were proved to have excellent adsorption performance for phosphate with a saturated capacity of 53.2 mg g^-1, which is over 12 times higher than that of pristine biochar beads. Although the particle size reduction, surface area, and O-containing group increments after milling are beneficial for adsorption, the remarkable promotion in performance should mainly result from the appropriate formation of magniferous crystals on biochar, which greatly accelerates the electrostatic interactions as well as precipitation for adsorption. The beads also exhibited excellent magnetism-driven recyclability, which greatly avoids secondary contamination and broadens the application field of the adsorbent.

SUBMITTER: Hu B

PROVIDER: S-EPMC10051089 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature

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Recyclable Magnesium-Modified Biochar Beads for Efficient Removal of Phosphate from Wastewater.

Hu Biao B Yan Nina N Zheng Zhiyu Z Xu Lei L Xie Hongde H Chen Jingwen J

Nanomaterials (Basel, Switzerland) 20230307 6

Although ball milling is effective for biochar modification with metal oxides for efficient phosphate removal, the recyclability of the adsorbent as well as the precursors for modification, still need to be optimized. Herein, a magnesium-modified biochar was first prepared with the precursor of MgCl2·6H2O through the solvent-free ball milling method. After that, recyclable biochar beads were fabricated with the introduction of sodium alginate and Fe3O4.</sub ...[more]

PMID: 36985860

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Project description:The treatment of wastewater containing heavy metals and the utilization of wool waste are very important for the sustainable development of textile mills. In this study, the wool keratin modified magnetite (Fe3O4) powders were fabricated by using wool waste via a co-precipitation technique for removal of Cu2+ ions from aqueous solutions. The morphology, chemical compositions, crystal structure, microstructure, magnetism properties, organic content, and specific surface area of as-fabricated powders were systematically characterized by various techniques including field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), vibrating sample magnetometer (VSM), thermogravimetric (TG) analysis, and Brunauer-Emmett-Teller (BET) surface area analyzer. The effects of experimental parameters such as the volume of wool keratin hydrolysate, the dosage of powder, the initial Cu2+ ion concentration, and the pH value of solution on the adsorption capacity of Cu2+ ions by the powders were examined. The experimental results indicated that the Cu2+ ion adsorption performance of the wool keratin modified Fe3O4 powders exhibited much better than that of the chitosan modified ones with a maximum Cu2+ adsorption capacity of 27.4 mg/g under favorable conditions (0.05 g powders; 50 mL of 40 mg/L CuSO4; pH 5; temperature 293 K). The high adsorption capacity towards Cu2+ ions on the wool keratin modified Fe3O4 powders was primarily because of the strong surface complexation of -COOH and -NH2 functional groups of wool keratins with Cu2+ ions. The Cu2+ ion adsorption process on the wool keratin modified Fe3O4 powders followed the Temkin adsorption isotherm model and the intraparticle diffusion and pseudo-second-order adsorption kinetic models. After Cu2+ ion removal, the wool keratin modified Fe3O4 powders were easily separated using a magnet from aqueous solution and efficiently regenerated using 0.5 M ethylene diamine tetraacetic acid (EDTA)-H2SO4 eluting. The wool keratin modified Fe3O4 powders possessed good regenerative performance after five cycles. This study provided a feasible way to utilize waste wool textiles for preparing magnetic biomass-based adsorbents for the removal of heavy metal ions from aqueous solutions.

Dataset Information

Recyclable Magnesium-Modified Biochar Beads for Efficient Removal of Phosphate from Wastewater.

Publications

Recyclable Magnesium-Modified Biochar Beads for Efficient Removal of Phosphate from Wastewater.

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