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Preparation of Amphiphilic Chitosan-Loaded Bentonite Adsorbent and Its Performance in Removing Organic Matter from Coking Wastewater.

ABSTRACT: An amphiphilic chitosan-loaded bentonite adsorbent (C18CTS-BT) was prepared for the efficient removal of organic matter from coking wastewater. The structure and surface morphology of adsorbents were characterized by FT-IR, XRD, and SEM. The removal of those organics by C18CTS-BT was investigated by comparing the adsorption performances of C18CTS-BT with bentonite (BT) and chitosan-loaded bentonite (CTS-BT). The results showed that compared with BT and CTS-BT, C18CTS-BT showed the performance advantages of having a low dosage, wide pH range, and short adsorption equilibrium time. The optimized treatment process was as follows: the adsorbent dosage was 1.5 g·L^-1, the adsorption time was 60 min, and the pH of the system was 7.0. The chemical oxygen demand (COD) of the coking wastewater treated with BT, CTS-BT, and C18CTS-BT decreased from 342 mg·L^-1 in the raw water to 264 mg·L^-1, 218 mg·L^-1, and 146 mg·L^-1, corresponding to COD removal rates of 22.81%, 36.26%, and 57.31%, respectively. The results of GC-MS analysis also confirmed that C18CTS-BT could remove most of the organic compounds in coking wastewater, especially long-chain alkanes and their derivatives. The hydrophobic modification of the adsorbent material can effectively improve the removal performance of organic compounds from coking wastewater.

SUBMITTER: Zhu Z

PROVIDER: S-EPMC10055804 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature

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Preparation of Amphiphilic Chitosan-Loaded Bentonite Adsorbent and Its Performance in Removing Organic Matter from Coking Wastewater.

Zhu Zhou Z Kou Haiqun H Zhou Yuchang Y Lan Xindian X Yu Meiying M Chen Haonan H

Polymers 20230322 6

An amphiphilic chitosan-loaded bentonite adsorbent (C18CTS-BT) was prepared for the efficient removal of organic matter from coking wastewater. The structure and surface morphology of adsorbents were characterized by FT-IR, XRD, and SEM. The removal of those organics by C18CTS-BT was investigated by comparing the adsorption performances of C18CTS-BT with bentonite (BT) and chitosan-loaded bentonite (CTS-BT). The results showed that compared with BT and CTS-BT, C18CTS-BT showed the performance ad ...[more]

PMID: 36987368

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Project description:Heavy metal ions in water refer to significant risks to the biological system due to their high toxicity. Therefore, the decontamination of water polluted by heavy metal ions attracts significant interest of researchers. Adsorption by nanomaterials has been a widely used technique for removing heavy metal ions from water. Chitosan was extracted from shrimp shellfish and mixed with laboratory-prepared AgNPs/GO in the ratio of 3 : 1. A series of tests evaluates the best condition of pH, amount of adsorbent, retention time, stirring speed, temp, and initial concentration. The research was conducted under various conditions. Langmuir, Freundlich, Tempkin, and Dubinin-Radushkevich isotherms were also tested. Also, the column adsorption experiment was carried out on industrial wastewater at different flow rates and column bed heights. The optimal values of the contact time, pH, and adsorbent dose of Cr(vi) were found to be 80 min, 4, and 0.1 g 100 mL-1, respectively, at room temperature (30 °C), agitation at 150 rpm, and initial concentration of 50 ppm. On the other hand, the optimal value of contact time, pH, and adsorbent dose of Fe(iii) were found to be 30 min, 6, and 0.02 g 100 mL-1, respectively, at room temp (30 °C) with a stirring speed of 250 rpm and an initial concentration of 40 ppm. For Cr(vi) and Fe(iii), equilibrium studies show that the data fit the Freundlich isotherm well (correlation coefficient, R 2 = 0.98) (III). A link between the pseudo-second order active model and data fitting the pseudo-first order active models were made. Within the intraparticle diffusion model, there are four stages that the mechanism must go through before it is at equilibrium. The adsorbent was tested in an industrial adsorbent column. This test proves that the nanocomposite's adsorption capacity can be restored by washing it with 0.1 M HCl, as shown by the periodicity test. After four cycles, the amount of Cr(vi) adsorbed on AgNPs/GO/chitosan was just 20%, which is insufficient for further adsorption experiments. Cr(vi) removal rates (%R) decreased slightly.

Dataset Information

Preparation of Amphiphilic Chitosan-Loaded Bentonite Adsorbent and Its Performance in Removing Organic Matter from Coking Wastewater.

Publications

Preparation of Amphiphilic Chitosan-Loaded Bentonite Adsorbent and Its Performance in Removing Organic Matter from Coking Wastewater.

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