Dataset Information

Ag₂NCN anchored on Ti₃C₂T_x MXene as a Schottky heterojunction: enhanced visible light photocatalytic efficiency of rhodamine B degradation.

ABSTRACT: The quick charge recombination of light-generated electrons and holes severely restricts the photocatalytic applications of single semiconductors. Here, a straightforward electrostatically driven self-assembly technique was used to construct an Ag₂NCN/Ti₃C₂T_x Schottky heterojunction, which was then used to degrade Rhodamine B (RhB) in the illumination of visible light. The findings from the experiments revealed that as a cocatalyst, Ti₃C₂T_x significantly suppresses the recombination rate and broadens visible absorptivity to improve Ag₂NCN photocatalytic efficiency. The optimized Ag₂NCN/Ti₃C₂T_x (AT2) composite exhibited an outstanding photocatalytic rate in 96 min, with the highest RhB degradation rate (k = 0.029 min^-1), which was around fifteen times that of pure Ag₂NCN (k = 0.002 min^-1). Furthermore, the trapping-agent experiment showed photogenerated superoxide radicals and holes were the principal active agents inside the photodegradation of RhB. Compared with Ag-based semiconductors, the composite exhibited outstanding photostability, highlighting its excellent potential for application in visible-light photocatalysis.

SUBMITTER: Yu H

PROVIDER: S-EPMC10251192 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature

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Ag2NCN anchored on Ti3C2Tx MXene as a Schottky heterojunction: enhanced visible light photocatalytic efficiency of rhodamine B degradation.

Yu Haidong H Jiang Haibing H Cao Xuan X Yao Shuhua S

RSC advances 20230501 24

The quick charge recombination of light-generated electrons and holes severely restricts the photocatalytic applications of single semiconductors. Here, a straightforward electrostatically driven self-assembly technique was used to construct an Ag2NCN/Ti3C2Tx Schottky heterojunction, which was then used to degrade Rhodamine B (RhB) in the illumination of visible light. The findings from the experiments revealed that as a cocatalyst, Ti3</su ...[more]

PMID: 37305443

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Project description:Background: The current clinical treatment of osteomyelitis is limited by the emergence of drug-resistant bacteria, which often leads to the failure of traditional antibiotic treatment and large bone defects. Sonodynamic therapy (SDT) is a new strategy that is widely used to overcome the problem of bacterial resistance to antibiotic therapy as well as poor tissue penetration using near-infrared light in photodynamic therapy (PDT). Therefore, it is necessary to develop a new sonosensitizer that can kill bacteria and promote bone repair. Methods: Herein, we developed a sonosensitizer, porphyrin metal-organic framework (HNTM), with a Schottky junction modified by Ti3C2 nanosheets (HN-Ti3C2) for highly efficient sonodynamic therapy of osteomyelitis and bone regeneration. Results: Ti3C2 greatly improves the acoustic catalytic performance by rapidly transferring the charge carriers generated by HNTM under ultrasound (US) irradiation, which killing drug-resistant bacteria through the generation of large amounts of reactive oxygen species (ROS). And HN-Ti3C2 shows excellent 99.75% antibacterial effectiveness against MRSA. In addition, HN-Ti3C2 generates a sonocurrent under low-intensity US to promote the repair of bone defects for a long time period. Mechanistic research using CCK-8 and RNA-seq showed that HN-Ti3C2 nanocomposites can promote the proliferation of stem cells by regulating the cell cycle, DNA replication, and apoptosis. In addition, after low-intensity US irradiation, HN-Ti3C2 promotes osteogenic differentiation via some key signaling pathways, including the calcium, Wnt, and TGF-beta signaling pathways, according to the Kyoto Encyclopedia of Genes and Genomes (KEGG). In a MRSA-infected rat tibial osteomyelitis model, HN-Ti3C2 successfully eliminated the infection and significantly improved bone regeneration under US irradiation. Conclusion: This study indicates that engineered HN-Ti3C2 is a distinctive nanocomposite for successful osteomyelitis treatment.

Dataset Information

Ag₂NCN anchored on Ti₃C₂T_x MXene as a Schottky heterojunction: enhanced visible light photocatalytic efficiency of rhodamine B degradation.

Publications

Ag<sub>2</sub>NCN anchored on Ti<sub>3</sub>C<sub>2</sub>T<sub><i>x</i></sub> MXene as a Schottky heterojunction: enhanced visible light photocatalytic efficiency of rhodamine B degradation.

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