Dataset Information

Semi-Interpenetrating Network Anion Exchange Membranes by Thiol-Ene Coupling Reaction for Alkaline Fuel Cells and Water Electrolyzers.

ABSTRACT: In this work, a thiol-ene coupling reaction was employed to prepare the semi-interpenetrating polymer network AEMs. The obtained QP-1/2 membrane exhibits high hydroxide conductivity (162.5 mS cm^-1 at 80 °C) with a relatively lower swelling ratio, demonstrating its mechanical strength of 42 MPa. This membrane is noteworthy for its improved alkaline stability, as the semi-interpenetrating network effectively limits the attack of hydroxide. Even after being treated in 2 M NaOH at 80 °C for 600 h, 82.5% of the hydroxide conductivity is maintained. The H₂/O₂ fuel cell with QP-1/2 membrane displays a peak power density of 521 mW cm^-2. Alkaline water electrolyzers based on QP-1/2 membrane demonstrated a current density of 1460 mA cm^-2 at a cell voltage of 2.00 V using NiCoFe catalysts in the anode. All the results demonstrate that a semi-interpenetrating structure is a promising way to enhance the mechanical property, ionic conductivity, and alkaline stability of AEMs for the application of alkaline fuel cells and water electrolyzers.

SUBMITTER: Jin Z

PROVIDER: S-EPMC10385286 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature

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Semi-Interpenetrating Network Anion Exchange Membranes by Thiol-Ene Coupling Reaction for Alkaline Fuel Cells and Water Electrolyzers.

Jin Zhiyu Z Zou Xiuyang X Xu Guodong G Sun Zhe Z Yan Feng F

Molecules (Basel, Switzerland) 20230717 14

In this work, a thiol-ene coupling reaction was employed to prepare the semi-interpenetrating polymer network AEMs. The obtained QP-1/2 membrane exhibits high hydroxide conductivity (162.5 mS cm<sup>-1</sup> at 80 °C) with a relatively lower swelling ratio, demonstrating its mechanical strength of 42 MPa. This membrane is noteworthy for its improved alkaline stability, as the semi-interpenetrating network effectively limits the attack of hydroxide. Even after being treated in 2 M NaOH at 80 °C f ...[more]

PMID: 37513341

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Project description:This Review provides an overview of the emerging concepts of catalysts, membranes, and membrane electrode assemblies (MEAs) for water electrolyzers with anion-exchange membranes (AEMs), also known as zero-gap alkaline water electrolyzers. Much of the recent progress is due to improvements in materials chemistry, MEA designs, and optimized operation conditions. Research on anion-exchange polymers (AEPs) has focused on the cationic head/backbone/side-chain structures and key properties such as ionic conductivity and alkaline stability. Several approaches, such as cross-linking, microphase, and organic/inorganic composites, have been proposed to improve the anion-exchange performance and the chemical and mechanical stability of AEMs. Numerous AEMs now exceed values of 0.1 S/cm (at 60-80 °C), although the stability specifically at temperatures exceeding 60 °C needs further enhancement. The oxygen evolution reaction (OER) is still a limiting factor. An analysis of thin-layer OER data suggests that NiFe-type catalysts have the highest activity. There is debate on the active-site mechanism of the NiFe catalysts, and their long-term stability needs to be understood. Addition of Co to NiFe increases the conductivity of these catalysts. The same analysis for the hydrogen evolution reaction (HER) shows carbon-supported Pt to be dominating, although PtNi alloys and clusters of Ni(OH)2 on Pt show competitive activities. Recent advances in forming and embedding well-dispersed Ru nanoparticles on functionalized high-surface-area carbon supports show promising HER activities. However, the stability of these catalysts under actual AEMWE operating conditions needs to be proven. The field is advancing rapidly but could benefit through the adaptation of new in situ techniques, standardized evaluation protocols for AEMWE conditions, and innovative catalyst-structure designs. Nevertheless, single AEM water electrolyzer cells have been operated for several thousand hours at temperatures and current densities as high as 60 °C and 1 A/cm2, respectively.

Dataset Information

Semi-Interpenetrating Network Anion Exchange Membranes by Thiol-Ene Coupling Reaction for Alkaline Fuel Cells and Water Electrolyzers.

Publications

Semi-Interpenetrating Network Anion Exchange Membranes by Thiol-Ene Coupling Reaction for Alkaline Fuel Cells and Water Electrolyzers.

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