Unknown

Dataset Information

0

Effect of Water and Carbon Dioxide on the Performance of Basolite Metal-Organic Frameworks for Methane Adsorption.

ABSTRACT: MOFs are potential adsorbents for methane separation from nitrogen, including recovery in diluted streams. However, water and carbon dioxide can seriously affect the adsorption performance. Three commercial MOFs, basolite C300, F300, and A100, were studied under similar conditions to fugitive methane streams, such as water (75 and 100% relative humidity) and carbon dioxide (0.33%) presence in a fixed bed. The presence of available open metal sites of copper (Cu2+) and aluminum (Al3+) in the case of basolite C300 and A100, respectively, constitutes a clear drawback under humid conditions, since water adsorbs on them, leading to significant methane capacity losses. Surprisingly, basolite F300 is the most resistant material due to its amorphous structure, which hinders water access. The combination of carbon dioxide and water creates a synergy that seriously affects basolite A100, closely related to its breathing effect, but does not constitute an important issue for basolite C300 and F300.

SUBMITTER: Ursueguia D 

PROVIDER: S-EPMC10561151 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Effect of Water and Carbon Dioxide on the Performance of Basolite Metal-Organic Frameworks for Methane Adsorption.

Ursueguía David D   Díaz Eva E   Ordóñez Salvador S  

Energy & fuels : an American Chemical Society journal 20230927 19

MOFs are potential adsorbents for methane separation from nitrogen, including recovery in diluted streams. However, water and carbon dioxide can seriously affect the adsorption performance. Three commercial MOFs, basolite C300, F300, and A100, were studied under similar conditions to fugitive methane streams, such as water (75 and 100% relative humidity) and carbon dioxide (0.33%) presence in a fixed bed. The presence of available open metal sites of copper (Cu<sup>2+</sup>) and aluminum (Al<sup  ...[more]

Similar Datasets

Unknown Monolithic metal-organic frameworks for carbon dioxide separation.
| S-EPMC8517963 | biostudies-literature
Unknown Synthesis and Characterization of 2D Metal-Organic Frameworks for Adsorption of Carbon Dioxide and Hydrogen.
| S-EPMC7674654 | biostudies-literature
Unknown Cooperative adsorption of carbon disulfide in diamine-appended metal-organic frameworks.
| S-EPMC6277438 | biostudies-literature
Unknown Predicting the Features of Methane Adsorption in Large Pore Metal-Organic Frameworks for Energy Storage.
| S-EPMC6215088 | biostudies-other
Unknown Synergistic electroreduction of carbon dioxide to carbon monoxide on bimetallic layered conjugated metal-organic frameworks.
| S-EPMC7075876 | biostudies-literature
Unknown Multiscale Theoretical Study of Sulfur Dioxide (SO<sub>2</sub>) Adsorption in Metal-Organic Frameworks.
| S-EPMC10096088 | biostudies-literature
Unknown Characterization of Adsorption Enthalpy of Novel Water-Stable Zeolites and Metal-Organic Frameworks.
| S-EPMC4726357 | biostudies-literature
Unknown Diatomite-Metal-Organic Framework Composite with Hierarchical Pore Structures for Adsorption/Desorption of Hydrogen, Carbon Dioxide and Water Vapor.
| S-EPMC7659967 | biostudies-literature
Unknown Made-to-order metal-organic frameworks for trace carbon dioxide removal and air capture.
| S-EPMC4083436 | biostudies-other
Unknown Structural Diversity and Carbon Dioxide Sorption Selectivity of Zinc(II) Metal-Organic Frameworks Based on Bis(1,2,4-triazol-1-yl)methane and Terephthalic Acid.
| S-EPMC9571910 | biostudies-literature