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ABSTRACT:
SUBMITTER: Montisci F
PROVIDER: S-EPMC10664187 | biostudies-literature | 2023 Nov
REPOSITORIES: biostudies-literature
Montisci Fabio F Lanza Arianna A Fisch Martin M Sonneville Camille C Geng Yan Y Decurtins Silvio S Reber Christian C Liu Shi-Xia SX Macchi Piero P
Physical chemistry chemical physics : PCCP 20231122 45
This study focuses on the effect of structure compression and cooling on the stereoelectronic properties of the planar π-conjugated TTF-BTD (TTF = tetrathiafulvalene; BTD = 2,1,3-benzothiadiazole) molecule, a prototypical example in which an electron-donor moiety is compactly annulated to an electron-acceptor moiety. Its partially oxidised iodine salt (TTF-BTD)<sub>2</sub>I<sub>3</sub> is a crystalline semiconductor featuring segregated columns of TTF<sup>+0.5</sup> units stacked <i>via</i> alte ...[more]