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(BEDT-TTF)2Cu2(HCOO)5: An Organic-Inorganic Hybrid Conducting Magnet.

ABSTRACT: A dual-functional organic-inorganic hybrid (BEDT-TTF)2Cu2(HCOO)5 (1) (BEDT-TTF=bis(ethylenedithio)tetrathiafulvalene) was obtained through the electrochemical oxidation of neutral BEDT-TTF in the presence of an ammonium salt of the one-dimensional copper-formate framework [(C2H5)3NH]2Cu2(HCOO)5 in a C6H5Cl-C2H5OH solution. Compound?1 was composed of organic donor BEDT-TTF+0?5 in a ?-phase arrangement and Jahn-Teller distorted (4,4) grid anion sheets [Cu2(HCOO)5-] n with S=1/2. We identified the material as a semiconductor with values of ?300K=10-1?S?cm-1. The anion sheet is a coordination isomer of [Cu2(HCOO)5-] n and, compared with the starting material, shows antiferromagnetic behavior as the well-known inorganic Cu-O, Co-O square layers for creating inorganic conducting magnets. Long-range antiferromagnetic ordering was observed at 8.0?K.

SUBMITTER: Zhang B 

PROVIDER: S-EPMC5474655 | biostudies-literature | 2017 Jun

REPOSITORIES: biostudies-literature

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(BEDT-TTF)<sub>2</sub>Cu<sub>2</sub>(HCOO)<sub>5</sub>: An Organic-Inorganic Hybrid Conducting Magnet.

Zhang Bin B   Zhang Yan Y   Wang Zheming Z   Gao Zengqiang Z   Yang Deliang D   Wang Dongwei D   Guo Yanjun Y   Zhu Daoben D  

ChemistryOpen 20170419 3

A dual-functional organic-inorganic hybrid (BEDT-TTF)<sub>2</sub>Cu<sub>2</sub>(HCOO)<sub>5</sub> (<b>1</b>) (BEDT-TTF=bis(ethylenedithio)tetrathiafulvalene) was obtained through the electrochemical oxidation of neutral BEDT-TTF in the presence of an ammonium salt of the one-dimensional copper-formate framework [(C<sub>2</sub>H<sub>5</sub>)<sub>3</sub>NH]<sub>2</sub>Cu<sub>2</sub>(HCOO)<sub>5</sub> in a C<sub>6</sub>H<sub>5</sub>Cl-C<sub>2</sub>H<sub>5</sub>OH solution. Compound <b>1</b> was com  ...[more]

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