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2,2'-Bipyridine Derivatives as Halogen Bond Acceptors in Multicomponent Crystals.


ABSTRACT: In this work, we present a systematic study of the halogen bonding potential of different 2,2'-bipyridine derivatives in the synthesis of cocrystals by using selected perfluorinated iodobenzenes and N-haloimides as halogen bond donors. These halogen bond acceptor molecules were chosen to explore how different substituents on 2,2'-bipyridine affect halogen bond formation. Out of 24 combinations, we obtained only 8 cocrystals by using two methods, liquid-assisted grinding and crystallization from the solution. Of those 8 cocrystals, one has already been described in the literature. As expected, structural data revealed that 2,2'-bipyridine derivatives act as ditopic halogen bond acceptors in all structures. Dominant interactions in 7 of the cocrystals are I···N or Br···N halogen bonds, while in the one remaining cocrystal it is the I···C(π) halogen bond.

SUBMITTER: Kucas F 

PROVIDER: S-EPMC10711937 | biostudies-literature | 2023 Dec

REPOSITORIES: biostudies-literature

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2,2'-Bipyridine Derivatives as Halogen Bond Acceptors in Multicomponent Crystals.

Kučas Filip F   Posavec Lidija L   Nemec Vinko V   Bedeković Nikola N   Cinčić Dominik D  

Crystal growth & design 20231109 12


In this work, we present a systematic study of the halogen bonding potential of different 2,2'-bipyridine derivatives in the synthesis of cocrystals by using selected perfluorinated iodobenzenes and <i>N</i>-haloimides as halogen bond donors. These halogen bond acceptor molecules were chosen to explore how different substituents on 2,2'-bipyridine affect halogen bond formation. Out of 24 combinations, we obtained only 8 cocrystals by using two methods, liquid-assisted grinding and crystallizatio  ...[more]

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